Weight | 190.195 g/mol |
---|---|
Formula | C8H14O5 |
Hydrogen Acceptors | 5 |
Hydrogen Donors | 1 |
Aromatic Rings | 0 |
Rotatable Bonds | 5 |
DIETHYL MALATE (7554-12-3)
diethyl malate, (R)-isomer · diethyl malate, (+-)-isomer · diethyl malate, (S)-isomer
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- Catalytic hydration of diethyl maleate to diethyl malate using divalent complexes of palladium(II) as catalysts (Organometallics, 1993)
- A cyclopropanol approach to the synthesis of the C13-C21 fragment of epothilones from diethyl (S)-malate (Tetrahedron Letters, 2005)
- Synthesis of (+)-disparlure from diethyl ()-malate via opening and fragmentation of the three-membered ring in tertiary cyclopropanols (Russian Journal of Organic Chemistry, 2009)
- Differentiation between the ethoxycarbonyl groups in diethyl malate via their titanium-catalyzed reductive cyclopropanation with ethylmagnesium bromide and subsequent site-selective three-carbon ring cleavage (Tetrahedron Letters, 2005)
- Association of substrates with alpha-chymotrypsin, diethyl alpha-acetoxysuccinate, and diethyl malate. (Journal of the American Chemical Society, 1966)
- Investigation for antimicrobial resistance-modulating activity of diethyl malate and 1-methyl malate against beta-lactamase class A from Bacillus licheniformis by molecular dynamics, in vitro and in vivo studies (Journal of Biomolecular Structure & Dynamics, 2015)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - diethyl malate, (R)-isomer
- diethyl malate, (+-)-isomer
- diethyl malate, (S)-isomer
-
SMILESCCOC(=O)CC(C(=O)OCC)O
-
InChIKeyVKNUORWMCINMRB-UHFFFAOYSA-N
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Synthesis
Reactant
+
ETHYL CHLOROFORMATE
(Grignard alcohol)
Reactant
+
Ethanol
(O-acylation)
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
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