1,4-Diazabicyclo[2.2.2]octane (280-57-9)

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  100 g
  $29.00

  500 g
  $116.00

  1 Kg
  $218.00

Most-cited Publications

• Quenching of singlet oxygen by tertiary aliphatic amines. Effect of DABCO (1,4-diazabicyclo[2.2.2]octane) (Journal of the American Chemical Society, 1968)
• Dabco-metalloporphyrin binding: ternary complexes, host-guest chemistry and the measurement of .pi.-.pi. interactions (Journal of the American Chemical Society, 1990)
• CuI-catalyzed suzuki-miyaura and sonogashira cross-coupling reactions using DABCO as ligand (Journal of Organic Chemistry, 2007)
• Site-selective fluorination of organic compounds using 1-alkyl-4-fluoro-1,4-diazabicyclo[2.2.2]octane salts (selectfluor reagents) (Journal of Organic Chemistry, 1993)
• DABCO-catalyzed coupling of aldehydes with activated double bonds. 4. Stereoselective synthesis of trisubstituted olefins and terpenoid building blocks via 2-(hydroxyalkyl)-2-propenoic esters (Journal of Organic Chemistry, 1985)
• Recyclable and reusable Pd(OAc)2/DABCO/PEG-400 system for Suzuki-Miyaura cross-coupling reaction. (Journal of Organic Chemistry, 2005)

Areas of Application

Safety

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  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H302: Harmful if swallowed
  Warning Acute toxicity, oral - Category 4
• H319: Causes serious eye irritation
  Warning Serious eye damage/eye irritation - Category 2A
• H371: May cause damage to organs
  Warning Specific target organ toxicity, single exposure - Category 2

Trends

Alternate Names

• DABCO
• triethylenediamine
• 1,4-diazabicyclo(2.2.2)octane
• 1,4-diazabicyclo-octane
• triethylenediamine diacetate
• DABCO cpd
• SMILES
  C1CN2CCN1CC2
• InChIKey
  IMNIMPAHZVJRPE-UHFFFAOYSA-N

External Links

• Pubchem - 1,4-Diazabicyclo[2.2.2]octane
• Wikipedia - triethylenediamine
  DABCO (1,4-diazabicyclo[2.2.2]octane) is an organic compound with the formula N2(C2H4)3. This colorless solid is a highly nucleophilic amine, which is used as a catalyst and reagent in polymerization and organic synthesis. Quinuclidine has a similar structure, with one of the nitrogen atoms replaced by a carbon atom.

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1,4-Diazabicyclo[2.2.2]octane

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