2,2-Dimethyl-1,3-dioxane-4,6-dione (2033-24-1)

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  25 g
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Most-cited Publications

• Structure of 3,6-dimethyl-1,4-dioxane-2,5-dione [D-,D-(L-,L-)lactide] (Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 1982)
• Vibrational optical activity of (3S,6S)-3,6-dimethyl-1,4-dioxane-2,5-dione (Journal of the American Chemical Society, 1996)
• Mechanism of fragmentation of alkylidene-Meldrum's acids: carboxyketene, vinylketene, and methyleneketene intermediates from 5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione (Journal of Organic Chemistry, 1985)
• Reaction of isopropylidene malonate with chloroimidates. A regiospecific formation of cyclic n-acylated -enamino esters. (Tetrahedron Letters, 1981)
• Some Applications of Isopropylidene Malonate and Its Derivatives to the Synthesis of Cyclic Compounds (Journal of Organic Chemistry, 1961)
• Reaction Between 5-Isopropylidene-2,2-dimethyl-1,3-dioxane-4,6-dione and tert-Butyl Isocyanide in the Presence of Primary or Secondary Amines (Monatshefte Fur Chemie, 2003)

Areas of Application

Safety

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Trends

Alternate Names

• Meldrum's acid
• cyclic isopropylidene malonate
• SMILES
  CC1(OC(=O)CC(=O)O1)C
• InChIKey
  GXHFUVWIGNLZSC-UHFFFAOYSA-N

External Links

• Pubchem - 2,2-Dimethyl-1,3-dioxane-4,6-dione
• Wikipedia - meldrum's acid
  Meldrum's acid or 2,2-dimethyl-1,3-dioxane-4,6-dione is an organic compound. The compound was first made in 1908 by Andrew Norman Meldrum by a condensation reaction of malonic acid with acetone in acetic anhydride and sulfuric acid. Meldrum misidentified the structure as a -lactone of -hydroxyisopropylmalonic acid but the correct structure is the dioxane derivative shown on this page.

Similar Compounds

2,2,5-Trimethyl-1,3-dioxane-4,6-dione (3709-18-0)

3 alternate names

3 suppliers

Diisopropyl malonate (13195-64-7)

3 alternate names

3 suppliers

5-(Methoxymethylene)-2,2-dimethyl-1,3-dioxane-4,6-dione (15568-85-1)

3 alternate names

3 suppliers

3-tert-Butoxy-3-oxopropanoic acid (40052-13-9)

3 alternate names

3 suppliers

Di-tert-butyl malonate (541-16-2)

3 alternate names

3 suppliers

tert-Butyl ethyl malonate (32864-38-3)

3 alternate names

3 suppliers

tert-Butyl methyl malonate (42726-73-8)

3 alternate names

3 suppliers

Ethyl potassium malonate (6148-64-7)

3 alternate names

3 suppliers

Ethyl hydrogen malonate (1071-46-1)

3 alternate names

3 suppliers

Ethyl 3,3-diethoxypropionate (10601-80-6)

3 alternate names

3 suppliers

DIETHYL MALONATE (105-53-3)

3 alternate names

2 safety hazards

3 suppliers

1,6-Dioxaspiro[4.4]nonane-2,7-dione (3505-67-7)

3 alternate names

3 suppliers

2,2-Dimethyl-5-phenyl-1,3-dioxane-4,6-dione (15231-78-4)

3 alternate names

3 suppliers

60234-78-8 (60234-78-8)

3 alternate names

3 suppliers

ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (6413-10-1)

3 alternate names

3 suppliers

NSC624349 (95422-24-5)

3 alternate names

3 suppliers

13937-08-1 (13937-08-1)

3 alternate names

3 suppliers

DIETHYL METHYLMALONATE (609-08-5)

3 alternate names

3 suppliers

Dioctyl malonate (16958-88-6)

3 alternate names

3 suppliers

51757-47-2 (51757-47-2)

3 alternate names

3 suppliers

5-(4-methoxybenzyl)-2,2-dimethyl-1,3-dioxane-4,6-dione (61958-46-1)

3 alternate names

3 suppliers

2,2-dimethyl-1,3-dioxan-5-amine (40137-24-4)

3 alternate names

3 suppliers

Triethyl methanetricarboxylate (6279-86-3)

3 alternate names

3 suppliers

Isopropyl acetoacetate (542-08-5)

3 alternate names

3 suppliers

3,3-diethoxypropanoic acid (6191-97-5)

3 alternate names

3 suppliers

Diethyl aminomalonate (6829-40-9)

3 alternate names

3 suppliers

Diethyl aminomalonate hydrochloride (13433-00-6)

3 alternate names

3 suppliers

Diethyl chloromalonate (14064-10-9)

3 alternate names

3 suppliers

3-ethoxy-2,2-dimethyl-3-oxopropanoic acid (5471-77-2)

3 alternate names

3 suppliers

Diethyl acetoxymalonate (5468-23-5)

3 alternate names

3 suppliers

ethyl 3-hydroxypropanoate (623-72-3)

3 alternate names

3 suppliers

Potassium 3-methoxy-3-oxopropanoate (38330-80-2)

3 alternate names

3 suppliers

tert-Butyl 3-hydroxybutanoate (90435-23-7)

3 alternate names

3 suppliers

21339-47-9 (21339-47-9)

3 alternate names

3 suppliers

Dimethyl malonate (108-59-8)

3 alternate names

3 suppliers

tert-butyl acetoacetate (1694-31-1)

3 alternate names

3 suppliers

Diethyl fluoromalonate (685-88-1)

3 alternate names

3 suppliers

2,2-Dimethyl-1,3-dioxolane-4-carbaldehyde (5736-03-8)

3 alternate names

3 suppliers

Diethyl bis(hydroxymethyl)malonate (20605-01-0)

3 alternate names

3 suppliers

Ethyl 2,2-diethoxypropionate (7476-20-2)

3 alternate names

3 suppliers

Methyl 3,3-dimethoxypropionate (7424-91-1)

3 alternate names

3 suppliers

Solketal (100-79-8)

3 alternate names

3 suppliers

DIETHYL ETHYLMALONATE (133-13-1)

3 alternate names

3 suppliers

Diethyl ketomalonate (609-09-6)

3 alternate names

3 suppliers

Diethyl bromomalonate (685-87-0)

3 alternate names

3 suppliers

tert-Butyl propionate (20487-40-5)

3 alternate names

1 safety hazard

3 suppliers

DIETHYL ISOPROPYLMALONATE (759-36-4)

3 alternate names

3 suppliers

Ethyl 3-hydroxybutyrate (35608-64-1, 5405-41-4)

3 alternate names

1 safety hazard

3 suppliers

5-(2-bromoethyl)-2,2-dimethyl-1,3-dioxane (97845-58-4)

3 alternate names

3 suppliers

DIETHYL PROPYLMALONATE (2163-48-6)

3 alternate names

3 suppliers

Dimethyl methylmalonate (609-02-9)

3 alternate names

3 suppliers

Diethyl formamidomalonate (6326-44-9)

3 alternate names

3 suppliers

tert-butyl pivalate (16474-43-4)

3 alternate names

3 suppliers

Methyl 2-oxotetrahydrofuran-3-carboxylate (19406-00-9)

3 alternate names

3 suppliers

Diethyl 2-(cyanomethyl)malonate (17109-93-2)

3 alternate names

3 suppliers

DIETHYL ISOBUTYLMALONATE (10203-58-4)

3 alternate names

3 suppliers

Diethyl allylmalonate (2049-80-1)

3 alternate names

3 suppliers

Diethyl ethylidenemalonate (1462-12-0)

3 alternate names

3 suppliers

25395-31-7 (25395-31-7, 102-62-5)

3 alternate names

3 suppliers

6296-99-7 (6296-99-7)

3 alternate names

3 suppliers

Diethyl acetylmalonate (570-08-1)

3 alternate names

3 suppliers

Diethyl butylmalonate (133-08-4)

3 alternate names

3 suppliers

ethyl acetoacetate (141-97-9)

3 alternate names

1 safety hazard

3 suppliers

triacetin (102-76-1)

3 alternate names

3 suppliers

tetraethyl hexane-1,1,6,6-tetracarboxylate (5394-84-3)

3 alternate names

3 suppliers

Diethyl 2-heptylmalonate (607-83-0)

3 alternate names

3 suppliers

36239-09-5 (36239-09-5)

3 alternate names

3 suppliers

Diethyl diethylmalonate (77-25-8)

3 alternate names

3 suppliers

7459-46-3 (7459-46-3)

3 alternate names

3 suppliers

Trimethyl methanetricarboxylate (1186-73-8)

3 alternate names

3 suppliers

16115-80-3 (16115-80-3)

3 alternate names

3 suppliers

Propyl acetoacetate (1779-60-8)

3 alternate names

3 suppliers

Butyl acetoacetate (591-60-6)

3 alternate names

1 safety hazard

3 suppliers

Tetraethyl 1,1,3,3-propanetetracarboxylate (2121-66-6)

3 alternate names

3 suppliers

Isopropyl 4,4,4-Trifluoroacetoacetate (175230-50-9)

3 alternate names

3 suppliers

Diethyl 2,2-difluoromalonate (680-65-9)

3 alternate names

3 suppliers

ethyl 2-amino-3-hydroxypropanoate hydrochloride (3940-27-0)

3 alternate names

3 suppliers

L-Serine ethyl ester hydrochloride (26348-61-8)

3 alternate names

3 suppliers

Diethyl isopropylidenemalonate (6802-75-1)

3 alternate names

3 suppliers

Diethyl 2-bromo-2-methylmalonate (29263-94-3)

3 alternate names

3 suppliers

3-Ethoxypropanoic acid (1331-11-9, 4324-38-3)

3 alternate names

3 suppliers

ethyl 2-chloro-3-oxopropanoate (33142-21-1)

3 alternate names

3 suppliers

tert-butyl butanoate (2308-38-5)

3 alternate names

3 suppliers

tert-Butyl cyanoacetate (1116-98-9)

3 alternate names

3 suppliers

2-O-Acetylmalic Anhydride (24766-96-9)

3 alternate names

3 suppliers

1,4-dioxane-2-carboxylic Acid (89364-41-0)

3 alternate names

3 suppliers

Diethyl (3-chloropropyl)malonate (18719-43-2)

3 alternate names

3 suppliers

Dimethyl chloromalonate (28868-76-0)

3 alternate names

3 suppliers

Dimethyl 2,2-dimethylmalonate (6065-54-9)

3 alternate names

3 suppliers

2318-25-4 (2318-25-4)

3 alternate names

3 suppliers

ethyl 3-ethoxy-3-iminopropanoate (27317-59-5)

3 alternate names

3 suppliers

(R)-1,2-Distearin (1429-59-0)

3 alternate names

3 suppliers

1,2-Dipalmitoyl-sn-glycerol (30334-71-5)

3 alternate names

3 suppliers

2-(Chloromethyl)-1,3-dioxane (5695-72-7)

3 alternate names

3 suppliers

3,3'-Oxydipropanoic acid (5961-83-1)

3 alternate names

3 suppliers

alpha-D-Glucose pentaacetate (604-68-2)

3 alternate names

3 suppliers

Methyl 3-methoxypropionate (3852-09-3)

3 alternate names

3 suppliers

Ethyl 3-hydroxy-3-methylbutanoate (18267-36-2)

3 alternate names

3 suppliers

3,3-dimethoxypropanoic Acid (6191-98-6)

3 alternate names

3 suppliers

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2,2-Dimethyl-1,3-dioxane-4,6-dione

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