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Diethyl ketomalonate
Weight174.152 g/mol
FormulaC7H10O5
Hydrogen Acceptors5
Hydrogen Donors0
Aromatic Rings0
Rotatable Bonds4

Diethyl ketomalonate (609-09-6)

diethyl mesoxalate  ·  diethyl mesoxalate hydrate

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Alternate Names

  • diethyl mesoxalate
  • diethyl mesoxalate hydrate
  • SMILES
    CCOC(=O)C(=O)C(=O)OCC
  • InChIKey
    DBKKFIIYQGGHJO-UHFFFAOYSA-N

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Synthesis

Ethyl cyanoformate  +  ETHYL CHLOROFORMATE (Grignard carbonyl)
Reactant  +  Ethanol (O-acylation)
Reactant  +  Chloroethane (Ester from carboxilic acid(SN2))
Reactant  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)
Synthesis of Diethyl ketomalonate ›

Similar Compounds

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2 safety hazards
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Ethyl hydrogen malonate (1071-46-1)
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Ethyl potassium malonate (6148-64-7)
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Diisopropyl malonate (13195-64-7)
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Dioctyl malonate (16958-88-6)
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tert-Butyl methyl malonate (42726-73-8)
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tert-Butyl ethyl malonate (32864-38-3)
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Di-tert-butyl malonate (541-16-2)
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13937-08-1 (13937-08-1)
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Diethyl oxalacetate (108-56-5)
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DIETHYL METHYLMALONATE (609-08-5)
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Dimethyl malonate (108-59-8)
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ethyl 2-oxobutanoate (15933-07-0)
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Ethyl bromopyruvate (70-23-5)
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7346-13-6 (7346-13-6)
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ethyl 3-hydroxypropanoate (623-72-3)
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METHYL PYRUVATE (600-22-6)
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Diethyl aminomalonate (6829-40-9)
3 alternate names
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Diethyl fluoromalonate (685-88-1)
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Diethyl chloromalonate (14064-10-9)
3 alternate names
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Diethyl bromomalonate (685-87-0)
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Ethyl 4-ethoxy-3-oxobutyrate (41051-14-3)
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Ethyl 2-oxovalerate (50461-74-0)
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Propyl acetoacetate (1779-60-8)
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Butyl acetoacetate (591-60-6)
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Tetronic acid (4971-56-6)
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Methyl 3-methoxypropionate (3852-09-3)
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ethyl acetoacetate (141-97-9)
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1 safety hazard
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Diethyl acetoxymalonate (5468-23-5)
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Dimethyl methylmalonate (609-02-9)
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Ethyl 3,3-diethoxypropionate (10601-80-6)
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DIETHYL ETHYLMALONATE (133-13-1)
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60234-78-8 (60234-78-8)
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ethyl 4-methyl-2-oxopentanoate (26073-09-6)
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3-Ethoxypropanoic acid (1331-11-9, 4324-38-3)
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2-Oxobutyl acetate (1575-57-1)
3 alternate names
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Ethyl 3-hydroxybutyrate (35608-64-1, 5405-41-4)
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1 safety hazard
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Trimethyl methanetricarboxylate (1186-73-8)
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16115-80-3 (16115-80-3)
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octyl 3-oxobutanoate (16436-00-3)
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Isopropyl acetoacetate (542-08-5)
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3,3'-Oxydipropanoic acid (5961-83-1)
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Methyl 2-oxobutanoate (3952-66-7)
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Diethyl acetylmalonate (570-08-1)
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Diethyl dibromomalonate (631-22-1)
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Ethyl 7-chloro-2-oxoheptanoate (78834-75-0)
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Diethyl 2,2-difluoromalonate (680-65-9)
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Dimethyl methoxymalonate (5018-30-4)
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Dimethyl 2,2-dimethylmalonate (6065-54-9)
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Allyl acetoacetate (1118-84-9)
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ethyl 3-ethoxy-3-iminopropanoate (27317-59-5)
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2318-25-4 (2318-25-4)
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PROPIONIC ANHYDRIDE (123-62-6)
3 alternate names
4 safety hazards
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DIETHYL ISOPROPYLMALONATE (759-36-4)
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Ethyl 3-amino-3-oxopropanoate (7597-56-0)
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36239-09-5 (36239-09-5)
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1,3-Diacetoxypropane (628-66-0)
3 alternate names
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Diethyl ethylidenemalonate (1462-12-0)
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759-65-9 (759-65-9)
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Ethyl propionylacetate (4949-44-4)
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Ethyl 2,4-dioxohexanoate (13246-52-1)
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6296-99-7 (6296-99-7)
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Propyl lactate (616-09-1)
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DIETHYL PROPYLMALONATE (2163-48-6)
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DIETHYL ISOBUTYLMALONATE (10203-58-4)
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Dimethyl chloromalonate (28868-76-0)
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ethyl cyclopropyl(oxo)acetate (519164-14-8)
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3-Allyloxypropionic Acid (22577-15-7)
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Ethyl 2-(hydroxymethyl)acrylate (10029-04-6)
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Diethyl diethylmalonate (77-25-8)
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tert-butyl acetoacetate (1694-31-1)
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Diethyl formamidomalonate (6326-44-9)
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Methyl 3-oxopropanoate (63857-17-0)
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ETHYL PROPIONATE (105-37-3)
3 alternate names
2 safety hazards
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Methyl 3-hydroxypropanoate (6149-41-3)
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Ethyl 4-chloroacetoacetate (638-07-3)
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Diethyl isopropylidenemalonate (6802-75-1)
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1-Acetoxy-3-chloroacetone (40235-68-5)
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Diethyl 2-(cyanomethyl)malonate (17109-93-2)
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ethyl 2-chloro-3-oxopropanoate (33142-21-1)
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Dibutyl oxalate (2050-60-4)
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Diethyl 1,3-acetonedicarboxylate (105-50-0)
3 alternate names
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105-50-0 (105-50-0)
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