2,5-Norbornadiene (121-46-0)

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Suppliers

• Sigma-Aldrich - 2,5-Norbornadiene
  30.40 - 390.00 USD
• Fisher Scientific - Search for 2,5-Norbornadiene
• TCI - 2,5-Norbornadiene
  38.00 - 364.00 USD

Most-cited Publications

• Living Polymerization of Phenylacetylenes Initiated by Rh(C.tplbond.CC6H5)(2,5-norbornadiene)[P(C6H5)3]2 (Journal of the American Chemical Society, 1994)
• Polymerization of monosubstituted acetylenes with a zwitterionic rhodium(I) complex, Rh+(2,5-norbornadiene)[.eta.6-C6H5)B-(C6H5)3] (Macromolecules, 1995)
• Expanding the C2-Symmetric Bicyclo[2.2.1]hepta-2,5-diene Ligand Family: Concise Synthesis and Catalytic Activity in Rhodium-Catalyzed Asymmetric Addition (Journal of Organic Chemistry, 2006)
• Effect of 2,5norbornadiene on abscission and ethylene production in citrus leaf explants (Physiologia Plantarum, 1985)
• Reactions of compounds of the type [(diene)RhX]2 (diene = cycloocta-1,5-diene, bicyclo[2.2.1]hepta-2,5-diene; X = Cl, Br) with tertiary phosphines and phosphites (Inorganic Chemistry, 1970)
• Some Reactions of 2,5-Norbornadiene (Bicyclo[2.2.1]-2,5-heptadiene)1 (Journal of the American Chemical Society, 1956)

Areas of Application

Safety

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Trends

Alternate Names

• bicyclo(2.2.1)hepta-2,5-diene
• SMILES
  C1C2C=CC1C=C2
• InChIKey
  SJYNFBVQFBRSIB-UHFFFAOYSA-N

External Links

• Pubchem - 2,5-Norbornadiene
• Wikipedia - 2,5-norbornadiene
  Norbornadiene is a bicyclic hydrocarbon and an organic compound. Norbornadiene is of interest as a metal-binding ligand, whose complexes are useful for homogeneous catalysis. It has been intensively studied owing to its high reactivity and distinctive structural property of being a diene that cannot isomerize (isomers would be anti-Bredt olefins).

Synthesis

42370-06-9  +  1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide (Nicolaou IBX dehydrogenation)

Synthesis of 2,5-Norbornadiene ›

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2,5-Norbornadiene

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