alpha-Methylstyrene (25014-31-7, 98-83-9)

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Suppliers

• Sigma-Aldrich - alpha-Methylstyrene
  31.40 - 40.50 USD
• Fisher Scientific - Search for alpha-Methylstyrene
• TCI - alpha-Methylstyrene
  14.00 - 17.00 USD

Most-cited Publications

• Interaction energies for blends of poly(methyl methacrylate), polystyrene, and poly(.alpha.-methylstyrene) by the critical molecular weight method (Macromolecules, 1993)
• Hydrogenation of .alpha.-methylstyrene by hydridopentacarbonylmanganese (I). Evidence for a free-radical mechanism (Journal of the American Chemical Society, 1977)
• Biotransformation of Ethyl Benzene, Styrene, and Alpha-Methyl sty rene in Man (American Industrial Hygiene Association Journal, 1970)
• Living cationic polymerization of .alpha.-methylstyrene initiated with a vinyl ether-hydrogen chloride adduct in conjunction with tin tetrabromide (Macromolecules, 1993)
• Some novel aspects of dimerization of .alpha.-methylstyrene with acidic ion-exchange resins, clays and other acidic materials as catalysts (Industrial & Engineering Chemistry Research, 1989)
• The synthesis, characterization, and deblocking of poly(4-tert-butoxystyrene) and poly(4-tert-butoxy-.alpha.-methylstyrene) (Macromolecules, 1989)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H226: Flammable liquid and vapor
  Warning Flammable liquids - Category 3
• H315: Causes skin irritation
  Warning Skin corrosion/irritation - Category 2
• H335: May cause respiratory irritation
  Warning Specific target organ toxicity, single exposure; Respiratory tract irritation - Category 3
• H372: Causes damage to organs through prolonged or repeated exposure
  Danger Specific target organ toxicity, repeated exposure - Category 1
• H411: Toxic to aquatic life with long lasting effects
  Hazardous to the aquatic environment, long-term hazard - Category 2

Trends

Alternate Names

• alpha-methyl-styrene
• alpha-methylstyrol
• 2-phenylpropene
• SMILES
  CC(=C)C1=CC=CC=C1
• InChIKey
  XYLMUPLGERFSHI-UHFFFAOYSA-N

External Links

• Pubchem - alpha-Methylstyrene
• Wikipedia - 2-phenylpropene
  -Methylstyrene (AMS) is a chemical intermediate used in the manufacture of plasticizers, resins and polymers. It is a co-product formed in a variation of the cumene process. The homopolymer obtained from this monomer, poly(-methylstyrene), is unstable, being characterized by a low ceiling temperature.

Synthesis

Reactant  +  1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide (Nicolaou IBX dehydrogenation)

Synthesis of alpha-Methylstyrene ›

Similar Compounds

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m,alpha-Dimethylstyrene (1124-20-5)

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m-Isopropenylchlorobenzene (1712-71-6)

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4-Methylstyrene (622-97-9, 1319-73-9, 24936-41-2)

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(2-BROMOETHYL)BENZENE (103-63-9, 31620-80-1)

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(4-Ethylphenyl)acetaldehyde (68083-54-5)

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1-Ethyl-2-methylbenzene (25550-14-5, 611-14-3 (2-ethyl toluene), 611-14-3)

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Propylbenzene (103-65-1)

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(2-Chloroethyl)benzene (1331-31-3, 622-24-2)

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1,3,5-TRIETHYLBENZENE (102-25-0, 102806-99-5)

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1,2-Diphenylethane (103-29-7, 38888-98-1)

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72927-80-1 (72927-80-1)

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19819-98-8 (19819-98-8)

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1633-22-3 (1633-22-3)

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(2,2-dibromovinyl)benzene (31780-26-4)

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1,3-Diphenylpropane (1081-75-0)

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4,4'-Dimethylbibenzyl (538-39-6)

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(3-Bromopropyl)benzene (637-59-2)

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68239-29-2 (68239-29-2)

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tert-Butylbenzene (98-06-6)

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phenelzine hydrochloride (77430-25-2, 5470-36-0)

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alpha-Methylstyrene

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