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Ethyl 4-(4-chlorophenyl)-2,4-dioxobutanoate
Weight254.669 g/mol
FormulaC12H11ClO4
Hydrogen Acceptors4
Hydrogen Donors0
Aromatic Rings1
Rotatable Bonds5

Ethyl 4-(4-chlorophenyl)-2,4-dioxobutanoate (5814-38-0)

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Alternate Names

  • SMILES
    CCOC(=O)C(=O)CC(=O)C1=CC=C(C=C1)Cl
  • InChIKey
    BDFNRYGGOPNIAG-UHFFFAOYSA-N

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Synthesis

CHLOROBENZENE  +  Ethyl 4-chloro-2,4-dioxobutanoate (Friedel-Crafts acylation)
Ethyl cyanoformate  +  2,4'-Dichloroacetophenone (Grignard carbonyl)
4-(4-chlorophenyl)-2,4-dioxobutanoic acid  +  Chloroethane (Ester from carboxilic acid(SN2))
Reactant  +  Ethanol (O-acylation)
Reactant  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)
Synthesis of Ethyl 4-(4-chlorophenyl)-2,4-dioxobutanoate ›

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