Hexafluoroacetone (684-16-2)

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Most-cited Publications

• POLYMERS DERIVED FROM HEXAFLUOROACETONE (Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics, 1989)
• Artificial Spinning and Characterization of Silk Fiber from Bombyx mori Silk Fibroin in Hexafluoroacetone Hydrate (Macromolecules, 2002)
• Direct measurement of Criegee intermediate (CH2OO) reactions with acetone, acetaldehyde, and hexafluoroacetone (Physical Chemistry Chemical Physics, 2012)
• Infrared, Raman and near-ultraviolet spectra of CF3COZ compoundsII. Hexafluoroacetone (Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 1965)
• Excited Singlet State Radiative and Nonradiative Transition Probabilities for Acetone, Acetoned6, and Hexafluoroacetone in the Gas Phase, in Solution, and in the Neat Liquid (Journal of Chemical Physics, 1971)
• Teflon-coated peptides: Hexafluoroacetone trihydrate as a structure stabilizer for peptides (Biopolymers, 1997)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H280: Contains gas under pressure; may explode if heated
  Warning Gases under pressure - Compressed gas, Liquefied gas, Dissolved gas
• H319: Causes serious eye irritation
  Warning Serious eye damage/eye irritation - Category 2A
• H361: Suspected of damaging fertility or the unborn child
  Warning Reproductive toxicity - Category 2
• H372: Causes damage to organs through prolonged or repeated exposure
  Danger Specific target organ toxicity, repeated exposure - Category 1

Trends

Alternate Names

• hexafluoroacetone sesquihydrate
• hexafluoroacetone dihydrate
• hexafluoroacetone hydrate
• hexafluoroacetone trihydrate
• hexafluoroacetone monohydrate
• SMILES
  C(=O)(C(F)(F)F)C(F)(F)F
• InChIKey
  VBZWSGALLODQNC-UHFFFAOYSA-N

External Links

• Pubchem - Hexafluoroacetone
• Wikipedia - hexafluoroacetone
  Hexafluoroacetone (HFA) is a chemical compound with the formula (CF3)2CO. It is structurally similar to acetone; however, its reactivity is markedly different. It a colourless, hygroscopic, nonflammable, highly reactive gas characterized by a musty odour.

Synthesis

1,1,1,3,3,3-Hexafluoro-2-propanol  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)

Trifluoroacetonitrile  +  Trifluoromethyl chloride (Grignard carbonyl)

Synthesis of Hexafluoroacetone ›

Similar Compounds

Hexafluoroacetone trihydrate (34202-69-2)

6 alternate names

3 suppliers

1,1,1-TRIFLUOROACETONE (421-50-1)

6 alternate names

3 suppliers

1,1,1,3,3,3-Hexafluoropropane (690-39-1)

6 alternate names

3 suppliers

3-Bromo-1,1,1-trifluoroacetone (431-35-6)

6 alternate names

3 suppliers

CHLOROPENTAFLUOROACETONE (79-53-8)

6 alternate names

3 suppliers

1,1,1-trifluoro-3-methylbutan-2-one (382-03-6)

6 alternate names

3 suppliers

1,1,1-Trifluoro-2-hexanone (360-34-9)

6 alternate names

3 suppliers

367-57-7 (367-57-7)

6 alternate names

3 suppliers

1,1,1-Trifluoro-2,4-pentanedione (367-57-7)

6 alternate names

3 suppliers

1,1-Dibromo-3,3,3-trifluoroacetone (431-67-4)

6 alternate names

3 suppliers

Trifluoroacetaldehyde (75-90-1)

6 alternate names

3 suppliers

Hexafluoroacetylacetone (1522-22-1)

6 alternate names

3 suppliers

1,1,1,2,3,3-Hexafluoropropane (431-63-0)

6 alternate names

3 suppliers

3,3,3-Trifluoropropanal (460-40-2)

6 alternate names

3 suppliers

Hexafluoroisobutylene (382-10-5)

6 alternate names

3 suppliers

1,1,1-Trichlorotrifluoroacetone (758-42-9)

6 alternate names

3 suppliers

1,1,1-Trifluoropropane (94458-05-6, 421-07-8)

6 alternate names

3 suppliers

2-Chloro-1,1,1,3,3,3-hexafluoropropane (431-87-8)

6 alternate names

3 suppliers

1,1,1,2,3-pentafluoropropane (431-31-2)

6 alternate names

3 suppliers

1,1,1-Trifluorohexane-2,4-dione (400-54-4)

6 alternate names

3 suppliers

Hexafluoroacetone imine (1645-75-6)

6 alternate names

3 suppliers

1,1,1,3,3-Pentafluorobutane (406-58-6)

6 alternate names

1 safety hazard

3 suppliers

38701-74-5 (38701-74-5)

6 alternate names

3 suppliers

1-Chloro-1,1,3,3,3-pentafluoropropane (460-92-4)

6 alternate names

3 suppliers

4,4,4-trifluorobutan-2-one (2366-70-3)

6 alternate names

3 suppliers

FLUOROACETONE (430-51-3)

6 alternate names

3 suppliers

Trifluoroacetyl fluoride (354-34-7)

6 alternate names

3 suppliers

2252-84-8 (2252-84-8, 33660-75-2)

6 alternate names

3 suppliers

1,3-Dichlorotetrafluoroacetone (127-21-9)

6 alternate names

3 suppliers

1,1,1-Trifluoropentane (406-82-6)

6 alternate names

3 suppliers

3-Chloro-1,1,1-trifluoropropane (460-35-5)

6 alternate names

3 suppliers

1,1-difluoropentane-2,4-dione (41739-23-5)

6 alternate names

3 suppliers

1,1,1-Trifluoro-6-methylheptane-2,4-dione (461-92-7)

6 alternate names

3 suppliers

1,1,1-Trifluoro-5-methylhexane-2,4-dione (30984-28-2)

6 alternate names

3 suppliers

30984-28-2 (30984-28-2)

6 alternate names

3 suppliers

Pentafluoropropionyl fluoride (422-61-7)

6 alternate names

3 suppliers

1,1,1,2,2,3-Hexafluoropropane (677-56-5)

6 alternate names

3 suppliers

Trifluoroacetamide (354-38-1)

6 alternate names

3 suppliers

Trifluoroacetyl chloride (354-32-5)

6 alternate names

3 suppliers

Mercury(II) trifluoroacetate (13257-51-7)

6 alternate names

3 suppliers

Sodium trifluoroacetate (2923-18-4)

6 alternate names

3 suppliers

Potassium trifluoroacetate (2923-16-2)

6 alternate names

3 suppliers

Thallium(III) trifluoroacetate (23586-53-0)

6 alternate names

3 suppliers

Silver trifluoroacetate (2966-50-9)

6 alternate names

3 suppliers

Ammonium trifluoroacetate (3336-58-1)

6 alternate names

3 suppliers

Trifluoroacetic acid (76-05-1)

6 alternate names

5 safety hazards

3 suppliers

Decafluoroisobutane (354-92-7)

6 alternate names

3 suppliers

3,3,3-Trifluoropropylamine (460-39-9)

6 alternate names

3 suppliers

1,1,1,4,4,4-Hexafluorobutane (407-59-0)

6 alternate names

3 suppliers

3,3,3-Trifluoro-1-propanol (65530-60-1, 2240-88-2)

6 alternate names

3 suppliers

1,1,1-Trifluoro-3-iodopropane (71215-70-8)

6 alternate names

3 suppliers

2-(Trifluoromethyl)propene (374-00-5)

6 alternate names

3 suppliers

1-Cyclohexyl-2,2,2-trifluoro-ethanone (6302-04-1)

6 alternate names

3 suppliers

1,1,1-Trifluoro-5,5-dimethylhexane-2,4-dione (22767-90-4)

6 alternate names

3 suppliers

(2,2,2-trifluoro-1-methylethyl)amine hydrochloride (2968-32-3)

6 alternate names

3 suppliers

hexafluoroisopropyl methyl ether (13171-18-1)

6 alternate names

3 suppliers

4-Chloro-1,1,1-trifluorobutane (406-85-9)

6 alternate names

3 suppliers

Pentafluoropropionaldehyde hydrate (422-06-0)

6 alternate names

3 suppliers

1,1-dichloro-1,3,3,3-tetrafluoropropane (64712-27-2)

6 alternate names

3 suppliers

Hexafluoro-2-methylisopropanol (1515-14-6)

6 alternate names

3 suppliers

3,3-Dichloro-1,1,1-trifluoropropane (460-69-5)

6 alternate names

3 suppliers

Perfluoro-tert-butanol (2378-02-1)

6 alternate names

3 suppliers

5-Bromo-1,1,1-trifluoropentane (54932-74-0)

6 alternate names

3 suppliers

1,1,1-Trifluoropropan-2-ol (374-01-6)

6 alternate names

3 suppliers

3,3,3-trifluoro-2-(trifluoromethyl)propanoic acid (564-10-3)

6 alternate names

3 suppliers

4,4,4-Trifluorobutanenitrile (690-95-9)

6 alternate names

3 suppliers

Perfluoroisobutylene (382-21-8)

6 alternate names

2 safety hazards

3 suppliers

1,1,1,2,2-PENTAFLUOROPROPANE (1814-88-6)

6 alternate names

3 suppliers

3,3,4,4,4-pentafluorobutan-2-one (374-41-4)

6 alternate names

3 suppliers

4,4,4-trifluorobutanamide (461-34-7)

6 alternate names

3 suppliers

4,4,4-Trifluoro-1-butanol (461-18-7)

6 alternate names

3 suppliers

4,4,4-Trifluorobutylamine (819-46-5)

6 alternate names

3 suppliers

4-Bromo-1,1,1-trifluorobutane (406-81-5)

6 alternate names

3 suppliers

84153-82-2 (84153-82-2)

6 alternate names

3 suppliers

Hexafluoroisopropyl trifluoroacetate (42031-15-2)

6 alternate names

3 suppliers

Heptafluoroisopropyl iodide (677-69-0)

6 alternate names

3 suppliers

1763-28-6 (1763-28-6)

6 alternate names

3 suppliers

METHYL TRIFLUOROACETATE (431-47-0)

6 alternate names

3 suppliers

2,3-Dichloro-1,1,1-trifluoropropane (338-75-0)

6 alternate names

3 suppliers

2,2,2-trifluoroacetohydrazide (1538-08-5)

6 alternate names

3 suppliers

N-Methyltrifluoroacetamide (815-06-5)

6 alternate names

3 suppliers

387-89-3 (387-89-3)

6 alternate names

3 suppliers

Ethyl 4,4,4-trifluoroacetoacetate (372-31-6)

6 alternate names

3 suppliers

1,2-DICHLORO-1,1,3,3,3-PENTAFLUOROPROPANE (431-86-7)

6 alternate names

3 suppliers

DIFLUOROACETIC ACID (381-73-7)

6 alternate names

3 suppliers

1,1,3-Trichlorotrifluoroacetone (79-52-7)

6 alternate names

3 suppliers

1,1,2,2,3-Pentafluoropropane (679-86-7)

6 alternate names

3 suppliers

1-Bromo-1,1,2,3,3,3-hexafluoropropane (2252-78-0)

6 alternate names

3 suppliers

381-84-0 (381-84-0)

6 alternate names

3 suppliers

Heptafluorobutyraldehyde (375-02-0)

6 alternate names

3 suppliers

Heptafluorobutyraldehyde hydrate (375-02-0)

6 alternate names

3 suppliers

1,1,1-Trifluoro-3-iodobutane (540-87-4)

6 alternate names

3 suppliers

Pyridine trifluoroacetate (464-05-1)

6 alternate names

3 suppliers

ETHYL TRIFLUOROACETATE (383-63-1)

6 alternate names

3 suppliers

Isopropyl trifluoroacetate (400-38-4)

6 alternate names

3 suppliers

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Hexafluoroacetone

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