| Weight | 167.33 g/mol |
|---|---|
| Formula | C6H18LiNSi2 |
| Hydrogen Acceptors | 0 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 0 |
| Rotatable Bonds | 2 |
Lithium bis(trimethylsilyl)amide (4039-32-1)
Li bis(TMS)A · (LiN(SiMe3)2)
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- Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides and Lithium Bis(trimethylsilyl)amide as an Ammonia Equivalent (Organic Letters, 2001)
- Bis(trimethylsilyl)amide und -methanide des Yttriums Moleklstrukturen von Tris(diethylether-O)lithium-(-chloro)-tris[bis(trimethylsilyl) methyl]yttriat, solvensfreiem Yttrium-tris[bis(trimethylsilyl)amid] sowie dem Bis(benzonitril)-Komplex (Zeitschrift fr anorganische und allgemeine Chemie, 1995)
- Palladium/ProazaphosphatraneCatalyzed Amination of Aryl Halides Possessing a Phenol, Alcohol, Acetanilide, Amide or an Enolizable Ketone Functional Group: Efficacy of Lithium Bis(trimethylsilyl)amide as the Base (Advanced Synthesis & Catalysis, 2004)
- Sodium Bis(trimethylsilyl)amide and Lithium Diisopropylamide in Deprotection of Alkyl Aryl Ethers: -Effect of Silicon (Journal of Organic Chemistry, 1997)
- Solvent effects on the aggregation of lithium bis(trimethylsilyl)amide (Journal of Organometallic Chemistry, 1971)
- Reaction of metallocene dichlorides of titanium(IV) and zirconium(IV) with lithium bis(trimethylsilyl)amide (Inorganic Chemistry, 1981)
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Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - Li bis(TMS)A
- (LiN(SiMe3)2)
-
SMILES[Li+].C[Si](C)(C)[N-][Si](C)(C)C
-
InChIKeyYNESATAKKCNGOF-UHFFFAOYSA-N
- Pubchem - Lithium bis(trimethylsilyl)amide
- Wikipedia - lithium hexamethyldisilazide
Lithium bis(trimethylsilyl)amide is a lithiated organosilicon compound with the formula LiN(SiMe3)2. It is commonly abbreviated as LiHMDS (lithium hexamethyldisilamide - a reference to its conjugate acid HMDS) and is primarily used as a strong non-nucleophilic base and as a ligand. Like many lithium reagents it has a tendency to aggregate and will form a cyclic trimer in the absence of coordinating species.
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Similar Compounds
Hexamethyldisilazane
(999-97-3)
3 alternate names
5 safety hazards
3 suppliers
Heptamethyldisilazane
(920-68-3)
3 alternate names
3 suppliers
7691-02-3
(7691-02-3)
3 alternate names
3 suppliers
N,N-Bis(trimethylsilyl)allylamine
(7688-51-9)
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azidotrimethylsilane
(4648-54-8)
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1009-93-4
(1009-93-4)
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2083-91-2
(2083-91-2)
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Trimethylsilyl isothiocyanate
(2290-65-5)
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3 suppliers
N-(Trimethylsilyl)acetamide
(13435-12-6)
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1,3-Bis(trimethylsilyl)urea
(18297-63-7)
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2,4,6-Trimethyl-2,4,6-trivinylcyclotrisilazane
(5505-72-6)
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TETRAMETHYLSILANE
(75-76-3)
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3 suppliers
996-50-9
(996-50-9)
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3 suppliers
Trimethylsilylmethanol
(3219-63-4)
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Bromotrimethylsilane
(2857-97-8)
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Iodotrimethylsilane
(16029-98-4)
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Chlorotrimethylsilane
(75-77-4)
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4 safety hazards
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FLUOROTRIMETHYLSILANE
(420-56-4)
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Trimethylsilanol
(1066-40-6)
3 alternate names
1 safety hazard
3 suppliers
20395-57-7
(20395-57-7)
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3 suppliers
2-(Trimethylsilyl)ethanol
(2916-68-9)
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3 suppliers
METHOXYTRIMETHYLSILANE
(1825-61-2)
3 alternate names
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N-Methyl-N-trimethylsilylacetamide
(7449-74-3)
3 alternate names
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N-Trimethylsilylaniline
(3768-55-6)
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Trimethylsilyl cyanide
(7677-24-9)
3 alternate names
3 suppliers
Vinyltrimethylsilane
(754-05-2)
3 alternate names
3 suppliers
Trimethylsilylacetylene
(1066-54-2)
3 alternate names
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(Iodomethyl)trimethylsilane
(4206-67-1)
3 alternate names
3 suppliers
(Bromomethyl)trimethylsilane
(18243-41-9)
3 alternate names
3 suppliers
Chloromethyltrimethylsilane
(2344-80-1)
3 alternate names
3 suppliers
51048-29-4
(51048-29-4)
3 alternate names
3 suppliers
Allyltrimethylsilane
(762-72-1)
3 alternate names
3 suppliers
4-(Trimethylsilyl)morpholine
(13368-42-8)
3 alternate names
3 suppliers
Hexamethyldisilane
(1450-14-2)
3 alternate names
3 suppliers
Dimethyldivinylsilane
(10519-87-6)
3 alternate names
3 suppliers
76513-69-4
(76513-69-4)
3 alternate names
3 suppliers
N,O-Bis(trimethylsilyl)acetamide
(10416-59-8)
3 alternate names
3 suppliers
N,O-Bis(trimethylsilyl)acetamide
(10416-59-8)
3 alternate names
3 suppliers
Dichlorodimethylsilane
(75-78-5)
3 alternate names
4 safety hazards
3 suppliers
Allyldimethylchlorosilane
(4028-23-3)
3 alternate names
3 suppliers
Trivinylmethylsilane
(18244-95-6)
3 alternate names
3 suppliers
Trimethylethoxysilane
(1825-62-3)
3 alternate names
3 suppliers
Chlorodimethylvinylsilane
(1719-58-0)
3 alternate names
3 suppliers
Chloro(chloromethyl)dimethylsilane
(1719-57-9)
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trimethyl(2-methylprop-2-en-1-yl)silane
(18292-38-1)
3 alternate names
3 suppliers
1833-53-0
(1833-53-0)
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3 suppliers
HEXAMETHYLDISILOXANE
(9006-65-9, 107-46-0)
3 alternate names
3 suppliers
Bis(diethylamino)dimethylsilane
(4669-59-4)
3 alternate names
3 suppliers
1-(Trimethylsilyl)-1-propyne
(6224-91-5)
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Bis(trimethylsilyl)acetylene
(14630-40-1)
3 alternate names
3 suppliers
5272-36-6
(5272-36-6)
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1,1-Dimethylsiletane
(2295-12-7)
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Tetraallylsilane
(1112-66-9)
3 alternate names
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1,3-Divinyltetramethyldisiloxane
(68083-19-2, 2627-95-4)
3 alternate names
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Sodium methylsiliconate
(31795-24-1, 16589-43-8)
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(Trifluoromethyl)trimethylsilane
(81290-20-2)
3 alternate names
3 suppliers
7381-30-8
(7381-30-8)
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MSTFA
(24589-78-4)
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3 suppliers
CHLOROTRIETHYLSILANE
(994-30-9)
3 alternate names
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2-Chloroethoxytrimethylsilane
(18157-17-0)
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TRIETHYLFLUOROSILANE
(358-43-0)
3 alternate names
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2-(trimethylsiloxy)-1,3-butadiene
(38053-91-7)
3 alternate names
3 suppliers
Tris(trimethylsilyl)methane
(1068-69-5)
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1-Chloroethyltrimethylsilane
(7787-87-3)
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1-(Trimethylsilyl)pyrrolidin-2-one
(14468-90-7)
3 alternate names
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3-BUTENYLTRIMETHYLSILANE
(763-13-3)
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DIMETHYLDIFLUOROSILANE
(353-66-2)
3 alternate names
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Dichloromethylvinylsilane
(124-70-9)
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3-Bromo-1-(trimethylsilyl)-1-propyne
(38002-45-8)
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1,4-Bis(trimethylsilyl)-1,3-butadiyne
(4526-07-2)
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Tris(trimethylsilyl) borate
(4325-85-3)
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14630-42-3
(14630-42-3)
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(Triethylsilyl)acetylene
(1777-03-3)
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4071-88-9
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79250-80-9
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Benzyltrimethylsilane
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Trimethylsilyl acetate
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5272-33-3
(5272-33-3)
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(((Chloromethyl)dimethylsilyl)methyl)trimethylsilane
(18306-73-5)
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1-Chloro-1-methylsiletane
(2351-34-0)
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1-Trimethylsilyl-1,4-pentadiyne
(71789-10-1)
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Dimethoxydimethylsilane
(1112-39-6)
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TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE
(18077-42-4)
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Tris(trimethylsilyloxy)ethylene
(69097-20-7)
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METHYLTRIS(TRIMETHYLSILOXY)SILANE
(17928-28-8)
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Methyltrimethoxysilane
(1185-55-3, 68584-81-6)
3 alternate names
3 safety hazards
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OCTAMETHYLTRISILOXANE
(63148-62-9, 107-51-7, 9006-65-9, 9016-00-6)
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Tert-Butyldimethylsilyl chloride
(18162-48-6)
3 alternate names
3 suppliers
Tetramethoxysilane
(12002-26-5, 681-84-5)
3 alternate names
3 safety hazards
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4-methoxybutan-2-one
(6975-85-5)
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Chloro(decyl)dimethylsilane
(38051-57-9)
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18643-08-8
(18643-08-8)
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N-(Trimethylsilyl)imidazole
(18156-74-6)
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1,2-Bis(chlorodimethylsilyl)ethane
(13528-93-3)
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Sodium dithionite
(7775-14-6)
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16260-48-3
(16260-48-3)
3 alternate names
3 suppliers
N-Trimethylsilyliminotriphenylphosphorane
(13892-06-3)
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1,3-Dichloro-1,1,3,3-tetramethyldisiloxane
(2401-73-2)
3 alternate names
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Triisopropylsilyl chloride
(13154-24-0)
3 alternate names
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Lithium bis(trimethylsilyl)amide
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