Weight | 99.209 g/mol |
---|---|
Formula | C4H9NSi |
Hydrogen Acceptors | 1 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 0 |
Trimethylsilyl cyanide (7677-24-9)
TMSCN
Score:
#7078 in Chemistry
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- Discovery of Chiral Catalysts through Ligand Diversity: TiCatalyzed Enantioselective Addition of TMSCN to meso Epoxides (Angewandte Chemie, 1996)
- THE ASYMMETRIC ADDITION OF TRIMETHYLSILYL CYANIDE TO ALDEHYDES CATALYZED BY CHIRAL (SALEN)TITANIUM COMPLEXES (Journal of the American Chemical Society, 1999)
- Synthetic applications of trimethylsilyl cyanide. Efficient synthesis of .beta.-aminomethyl alcohols (Journal of Organic Chemistry, 1974)
- Activation of TMSCN by N-Heterocyclic Carbenes for Facile Cyanosilylation of Carbonyl Compounds. (Journal of Organic Chemistry, 2006)
- Optimized catalysts for the asymmetric addition of trimethylsilyl cyanide to aldehydes and ketones (Tetrahedron, 2001)
- Asymmetric Ring Opening of Meso Epoxides with TMSCN Catalyzed by (pybox)lanthanide Complexes (Organic Letters, 2000)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - TMSCN
-
SMILESC[Si](C)(C)C#N
-
InChIKeyLEIMLDGFXIOXMT-UHFFFAOYSA-N
- Pubchem - Trimethylsilyl cyanide
- Wikipedia - Trimethylsilyl cyanide
Trimethylsilyl cyanide is the chemical compound with the formula (CH3)3SiCN. This volatile liquid consists of a cyanide group, that is CN, attached to a trimethylsilyl group. The molecule is used in organic synthesis as the equivalent of hydrogen cyanide.
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