Weight | 144.126 g/mol |
---|---|
Formula | C6H8O4 |
Hydrogen Acceptors | 4 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 3 |
Methyl 2,4-dioxopentanoate (20577-61-1)
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- Synthetic Photochemistry. XXXIV. Synthetic Strategy of 5-8-5-Membered Tricyclic Higher Terpenoids Based on the Condensation of Two Optically-Active Iridoids, C10-Synthons Obtained from Photo-Cycloadduct of Methyl 2,4-DioxopentanoateIsoprene, and Its Application to a Synthesis of the Basic Carbon Skeleton of Fusicoccane (Bulletin of the Chemical Society of Japan, 1986)
- Synthetic photochemistry. LI. Structure elucidation of the pyrolysates formed by "retro-benzilic acid rearrangement" of the proto-photocycloadducts of methyl 2,4-dioxopentanoate-olefins. (Bulletin of the Chemical Society of Japan, 1989)
- Synthetic photochemistry. XXVIII: A photochemical C5-homologation of 4-isopropenyltoluene with methyl 2,4-dioxopentanoate to isolaurene and a formal synthesis of cuparene (Bulletin of the Chemical Society of Japan, 1984)
- Synthetic photochemistry. LXIV. Mild base-induced retro-benzilic-acid rearrangement of isolated proto-photocycloadducts of methyl 2,4-dioxopentanoate to terpinolene. Facile synthesis of -chamigrene and -chamigren-3-one (Bulletin of the Chemical Society of Japan, 1994)
- Synthetic Photochemistry. LIV. The Photoaddition Reaction of Methyl 2,4-Dioxopentanoate with 2,5-Dimethyl-2,4-hexadiene, a Sterically Crowded Conjugated Diene (Bulletin of the Chemical Society of Japan, 1990)
- Synthetic Photochemistry. XXIX. A Convenient Preparation of 1,2,3-Substituted Cyclopentenes from the Photoadducts of Methyl 2,4-DioxopentanoateIsoprene (Bulletin of the Chemical Society of Japan, 1985)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. -
SMILESCC(=O)CC(=O)C(=O)OC
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InChIKeyOMHOEQINEXASKE-UHFFFAOYSA-N
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Synthesis
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
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