| Weight | 100.117 g/mol |
|---|---|
| Formula | C5H8O2 |
| Hydrogen Acceptors | 2 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 0 |
| Rotatable Bonds | 1 |
Methyl crotonate (18707-60-3, 623-43-8)
Score:
#2048 in Physics
,
#6386 in Chemistry
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- Asymmetric Michael reactions of 3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepine with methyl crotonate (Journal of Organic Chemistry, 1986)
- Michael addition of methyl crotonate over solid base catalysts (Applied Catalysis A-general, 1997)
- [2 + 2] Cycloadditions of silyl enol ethers and dimethyl acetylenedicarboxylate, dimethyl fumarate, and methyl crotonate (Journal of Organic Chemistry, 1979)
- Preparation and Characterization of Head-to-Head Polymers. III. Head-to-Head Poly (methyl Crotonate) (Journal of Macromolecular Science, Part A, 1974)
- Highly stereodivergent generation of the Z- and E-enolates of a -amino ester via conjugate addition to methyl crotonate by using lithium N-benzyltrimethylsilylamide as a nitrogen nucleophile, and application to stereoselective aldol reactions (Journal of The Chemical Society, Chemical Communications, 1989)
- Preparation of Disyndiotactic Poly(methyl crotonate) by Stereospecific Group Transfer Polymerization (Polymer Journal, 1999)
-
Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. -
SMILESCC=CC(=O)OC
-
InChIKeyMCVVUJPXSBQTRZ-UHFFFAOYSA-N
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Synthesis
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
Reactant
+
1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide
(Nicolaou IBX dehydrogenation)
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Methyl crotonate
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