Weight | 430.494 g/mol |
---|---|
Formula | Br5P |
Hydrogen Acceptors | 0 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 0 |
Phosphorus pentabromide (7789-69-7)
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- Sigma-Aldrich - Phosphorus pentabromide85.30 - 234.50 USD
- Fisher Scientific - Search for Phosphorus pentabromide
- TCI - Search for Phosphorus pentabromide
- Mechanism of the von Braun amide degradations with carbonyl bromide or phosphorus pentabromide (Tetrahedron, 1973)
- Crystal Structure of Phosphorus Pentabromide (Nature, 1940)
- Refinement of the crystal structure of phosphorus pentabromide, PBr5 (Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 1970)
- Conformational Analysis. V. The Reaction of cis- and trans-4-t-Butylcyclohexanol and trans-4-Methylcyclohexanol with Phosphorus Pentabromide. Syntheses of Alkylcyclohexyl Bromides1 (Journal of Organic Chemistry, 1959)
- The crystal structure of phosphorus pentabromide (Recueil des Travaux Chimiques des Pays-Bas, 2010)
- Raman spectra of phosphorus pentabromide, phosphorus heptabromide and caesium tribromide (Recueil des Travaux Chimiques des Pays-Bas, 2010)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. -
SMILESP(Br)(Br)(Br)(Br)Br
-
InChIKeyQRKVRHZNLKTPGF-UHFFFAOYSA-N
- Pubchem - Phosphorus pentabromide
- Wikipedia - phosphorus pentabromide
Phosphorus pentabromide is a reactive, yellow solid of formula PBr5, which has the structure PBr4+ Br in the solid state but in the vapor phase is completely dissociated to PBr3 and Br2. Rapid cooling of this phase to 15K leads to formation of the ionic species phosphorus heptabromide ([PBr4]+[Br3]). It can be used in organic chemistry to convert carboxylic acids to acyl bromides.
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