2,2'-Dichlorodiethyl ether (111-44-4)

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  50 g
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Most-cited Publications

• Excess properties of the mixture bis(2-dichloroethyl)ether (chlorex) + 2,2,4-trimethylpentane (isooctane) (Monatshefte Fur Chemie, 1987)
• Synthesis of bis(aryloxyethyl) vinyl ethers via phase-transfer-catalyzed nucleophilic displacement on 2-chloroethyl vinyl ether (Journal of Organic Chemistry, 1983)
• Synthesis of Highly Reactive Polyisobutylene Catalyzed by EtAlCl 2 / Bis(2-chloroethyl) Ether Soluble Complex in Hexanes (Macromolecules, 2014)
• Study of diffusion and sorption of bis-(2-chloroethyl)sulfide (SM) and bis-(2-chloroethyl)ether (OM) through polypropylene (PP) and biaxial-oriented polypropylene (BOPP) films by the FTIR-ATR spectroscopic method (Journal of Applied Polymer Science, 1996)
• Identification of S-(carboxymethyl)-l-cysteine and thiodiglycollic acid, urinary metabolites of 2,2-bis-(chloroethyl)-ether in the rat (Cancer Letters, 1979)
• Hydrolysis and Oxidation Products of the Chemical Warfare Agents 1,2-Bis[(2-chloroethyl)thio]ethane Q and 2,2-Bis(2-chloroethylthio)diethyl Ether T (Phosphorus Sulfur and Silicon and The Related Elements, 2003)

Areas of Application

Safety

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  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H226: Flammable liquid and vapor
  Warning Flammable liquids - Category 3
• H300: Fatal if swallowed
  Danger Acute toxicity, oral - Category 1, 2
• H311: Toxic in contact with skin
  Danger Acute toxicity, dermal - Category 3
• H320: Causes eye irritation
  Warning Serious eye damage/eye irritation - Category 2B
• H330: Fatal if inhaled
  Danger Acute toxicity, inhalation - Category 1, 2
• H370: Causes damage to organs
  Danger Specific target organ toxicity, single exposure - Category 1

Trends

Alternate Names

• Chlorex
• bis(2-chloroethyl)ether
• SMILES
  C(CCl)OCCCl
• InChIKey
  ZNSMNVMLTJELDZ-UHFFFAOYSA-N

Estimated Properties

External Links

• Pubchem - 2,2'-Dichlorodiethyl ether
• Wikipedia - bis(2-chloroethyl)ether
  Bis(chloroethyl) ether is a chemical compound (an ether), which contains two 2-chloroethyl groups. It is a clear liquid with the odor of a chlorinated solvent.

Synthesis

2-chloroethanol  +  1,2-dichloroethane (Williamson ether)

Synthesis of 2,2'-Dichlorodiethyl ether ›

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2,2'-Dichlorodiethyl ether

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