Weight | 226.316 g/mol |
---|---|
Formula | C13H22O3 |
Hydrogen Acceptors | 3 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 6 |
24851-98-7 (24851-98-7)
methyldihydrojasmonate · Hedione · (+)-(1R,2S)-methyl dihydrojasmonate
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- Synthesis of cisHedione and Methyl Jasmonate via Cascade BaylisHillman Reaction and Claisen Ortho Ester Rearrangement (Helvetica Chimica Acta, 2005)
- The smelling of Hedione results in sex-differentiated human brain activity (NeuroImage, 2015)
- Methyl Homologues of Methyl Jasmonate and Methyl Dihydrojasmonate (Hedione) from Sorbyl Alcohol (Helvetica Chimica Acta, 2004)
- The Jubilee of Methyl Jasmonate and Hedione (Helvetica Chimica Acta, 2012)
- Further Explorations into the Synthesis of DehydroHedione (Helvetica Chimica Acta, 2013)
- Methyl Homologues of Methyl Jasmonate and Methyl Dihydrojasmonate (Hedione) from Sorbyl Alcohol. (ChemInform, 2004)
-
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - methyldihydrojasmonate
- Hedione
- (+)-(1R,2S)-methyl dihydrojasmonate
-
SMILESCCCCCC1C(CCC1=O)CC(=O)OC
-
InChIKeyKVWWIYGFBYDJQC-UHFFFAOYSA-N
- Pubchem - 24851-98-7
- Wikipedia - Methyl dihydrojasmonate
Methyl dihydrojasmonate is an aroma compound, that smells vaguely similar to jasmine. In racemic mixtures the odor is floral and citrus while epimerized mixtures exhibit a dense fatty floral odor with odor recognition thresholds of 15 parts per billion. The compound is also known as hedione.
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Synthesis
methyl 2-(3-hydroxy-2-pentylcyclopentyl)acetate
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
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