GLYCIDYL METHACRYLATE (25067-05-4, 106-91-2)

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Suppliers

• Sigma-Aldrich - GLYCIDYL METHACRYLATE
  30.50 - 511.00 USD
• Fisher Scientific - Search for GLYCIDYL METHACRYLATE
• TCI - GLYCIDYL METHACRYLATE
  21.00 - 75.00 USD

Most-cited Publications

• Synthesis, Characterization, and Polymerization of Glycidyl Methacrylate Derivatized Dextran (Macromolecules, 1995)
• Biologically active polymers. V. Synthesis and antimicrobial activity of modified poly(glycidyl methacrylateco2hydroxyethyl methacrylate) derivatives with quaternary ammonium and phosphonium salts (Journal of Polymer Science Part A, 2002)
• Molded Macroporous Poly(glycidyl methacrylate-co-trimethylolpropane trimethacrylate) Materials with Fine Controlled Porous Properties: Preparation of Monoliths Using Photoinitiated Polymerization (Chemistry of Materials, 1997)
• Reaction of Dextran with Glycidyl Methacrylate: An Unexpected Transesterification (Macromolecules, 1997)
• Covalent Immobilization of Glucose Oxidase on Well-Defined Poly(glycidyl methacrylate)Si(111) Hybrids from Surface-Initiated Atom-Transfer Radical Polymerization (Biomacromolecules, 2005)
• Effect of glycidyl methacrylate (GMA) on the thermal, mechanical and morphological property of biodegradable PLA/PBAT blend and its nanocomposites. (Bioresource Technology, 2010)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H227: Combustible liquid
  Warning Flammable liquids - Category 4
• H302: Harmful if swallowed
  Warning Acute toxicity, oral - Category 4
• H311: Toxic in contact with skin
  Danger Acute toxicity, dermal - Category 3
• H315: Causes skin irritation
  Warning Skin corrosion/irritation - Category 2
• H317: May cause an allergic skin reaction
  Warning Sensitization, Skin - Category 1
• H319: Causes serious eye irritation
  Warning Serious eye damage/eye irritation - Category 2A
• H341: Suspected of causing genetic defects
  Warning Germ cell mutagenicity - Category 2
• H370: Causes damage to organs
  Danger Specific target organ toxicity, single exposure - Category 1
• H401: Toxic to aquatic life
  Hazardous to the aquatic environment, acute hazard - Category 2

Trends

Alternate Names

• 2,3-epoxypropyl methacrylate
• monomethacrylate propylene oxide
• Sta-Lock
• SMILES
  CC(=C)C(=O)OCC1CO1
• InChIKey
  VOZRXNHHFUQHIL-UHFFFAOYSA-N

External Links

• Pubchem - GLYCIDYL METHACRYLATE
• Wikipedia - glycidyl methacrylate
  Glycidyl methacrylate (GMA) is an ester of methacrylic acid and glycidol, it is a common monomer used in the creation of epoxy resins. While typical home epoxies contain diglycidyl ether of bisphenol A (DGEBA), glycidyl methacrylate is instead used to provide epoxy functionalization to polyolefins and other acrylate resins. Glycidyl methacrylate is produced by several companies worldwide, including Dow Chemical.

Synthesis

METHACRYLIC ACID  +  Epichlorohydrin (Ester from carboxilic acid(SN2))

METHACRYLOYL CHLORIDE  +  GLYCIDOL (O-acylation)

Reactant  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)

Reactant  +  1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide (Nicolaou IBX dehydrogenation)

Synthesis of GLYCIDYL METHACRYLATE ›

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GLYCIDYL METHACRYLATE

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