N-METHYLFORMAMIDE (123-39-7)

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Suppliers

• Sigma-Aldrich - N-METHYLFORMAMIDE
  28.10 - 190.00 USD
• Fisher Scientific - Search for N-METHYLFORMAMIDE
• TCI - N-METHYLFORMAMIDE
  14.00 - 42.00 USD

Most-cited Publications

• Femtosecond dynamics of hydrogenbonding solvents. Formamide and Nmethylformamide in acetonitrile, DMF, and water (Journal of Chemical Physics, 1993)
• N-methylformamide as a separation medium in capillary electrophoresis (Chromatographia, 1995)
• The dynamics of liquid formamide, N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide. A dielectric relaxation study (Journal of Molecular Liquids, 2002)
• Molecular Structure of N-Methylformamide as Studied by Gas Electron Diffraction (Bulletin of the Chemical Society of Japan, 1974)
• Liquid crystal-isotropic phase equilibriums in the system poly(.gamma.-benzyl .alpha.-L-glutamate)-methylformamide (The Journal of Physical Chemistry, 1971)
• Theoretical study of hydrogen bonding in liquid and gaseous N- methylformamide (Journal of Chemical Physics, 1997)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H312: Harmful in contact with skin
  Warning Acute toxicity, dermal - Category 4

Trends

Alternate Names

• methylformamide
• monomethylformamide
• NSC 3051
• SMILES
  CNC=O
• InChIKey
  ATHHXGZTWNVVOU-UHFFFAOYSA-N

External Links

• Pubchem - N-METHYLFORMAMIDE
• Wikipedia - N-methylformamide
  N-Methylformamide (NMF) is a colorless, nearly odorless, organic compound with molecular formula CH3NHCHO, which is a liquid at room temperature. NMF is mainly used as a reagent in various organic syntheses with limited applications as a highly polar solvent. NMF is closely related to other formamides, notably formamide and dimethylformamide (DMF).

Synthesis

Methylboronic acid  +  Formylaminoradical (Chan-Lam coupling reaction)

Methylaminomethanol  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)

Synthesis of N-METHYLFORMAMIDE ›

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formamide (75-12-7)

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METHYLUREA (598-50-5)

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N-Ethylformamide (627-45-2)

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1,3-DIMETHYLUREA (96-31-1)

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Methylaminoformyl chloride (6452-47-7)

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N-METHYLACETAMIDE (79-16-3)

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Dimethylamine (124-40-3, 6912-12-5)

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53170-19-7 (53170-19-7)

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1,1-DIMETHYLUREA (598-94-7, 1320-50-9)

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Urea hydrogen peroxide (124-43-6)

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Formylhydrazine (624-84-0)

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n-allylformamide (16250-37-6)

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N-ETHYLACETAMIDE (625-50-3)

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Ethylurea (625-52-5, 9009-54-5)

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Methylolurea (1000-82-4, 78200-36-9)

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AMMONIUM CARBAMATE (1111-78-0)

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DIMETHYLCARBAMOYL CHLORIDE (79-44-7)

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Trimethylamine hydrochloride (593-81-7)

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Tetramethylammonium formate (59138-84-0)

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trimethylamine (75-50-3)

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N,N-DIMETHYLACETAMIDE (127-19-5)

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n-methylhydrazinecarboxamide (17696-95-6)

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2-amino-N-methylacetamide hydrochloride (49755-94-4)

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2-Amino-N-methylacetamide (22356-89-4)

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N-(Hydroxymethyl)acetamide (625-51-4)

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Trimethylurea (632-14-4)

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N-Vinylacetamide (28408-65-3, 5202-78-8)

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Tetramethylammonium hydroxide pentahydrate (10424-65-4)

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2-Chloro-N-methylacetamide (96-30-0)

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Tetramethylammonium iodide (75-58-1)

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Tetramethylammonium bromide (64-20-0)

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TETRAMETHYLAMMONIUM CHLORIDE (75-57-0)

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TETRAMETHYLUREA (632-22-4)

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1,2-Diformylhydrazine (628-36-4)

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1-methylhydrazinecarboxamide (22718-48-5)

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2-hydroxy-n-methylacetamide (5415-94-1)

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2-bromo-N-methylacetamide (34680-81-4)

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N-(2-Aminoethyl)acetamide (1001-53-2)

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Methylenediurea (13547-17-6)

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azetidin-2-one (930-21-2)

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2-Chloroacetamide (79-07-2)

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1,3-Diethylurea (50816-31-4, 623-76-7)

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N-(2-Hydroxyethyl)-N-methylformamide (1590-50-7)

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Glycinamide hydrochloride (1668-10-6)

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33797-51-2 (33797-51-2)

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N-methyl-2-(methylamino)acetamide (44565-47-1)

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SEMICARBAZIDE HYDROCHLORIDE (563-41-7)

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N-PROPYLACETAMIDE (5331-48-6)

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1,1-DIMETHYLHYDRAZINE (30260-66-3, 57-14-7)

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30354-18-8 (30354-18-8)

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ISOPROPYLUREA (691-60-1)

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N-(Cyanomethyl)acetamide (4814-80-6)

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N-(2-Chloroethyl)acetamide (7355-58-0)

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N-(2-Hydroxyethyl)acetamide (142-26-7)

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N-Propylurea (627-06-5)

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N,N-dimethylhydrazinecarboxamide (40685-92-5)

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N,N'-Diacetylethylenediamine (871-78-3)

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METHYL CARBAMATE (598-55-0)

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Tetramethylammonium acetate (10581-12-1)

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(methylsulfanyl)formamide (21325-07-5)

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2-Hydroxyethylurea (2078-71-9, 1320-51-0)

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2-Imidazolidone (120-93-4)

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2-Amino-N,N-dimethylacetamide hydrochloride (72287-77-5)

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Sodium dicyanamide (1934-75-4)

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Diethylamine N-d1 (997-11-5)

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Diethylamine hydrochloride (660-68-4)

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2,2-Dichloroacetamide (683-72-7)

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3162-58-1 (17736-86-6, 3162-58-1)

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ACRYLAMIDE (79-06-1, 122775-19-3, 9082-06-8, 9003-05-8, 79-06-1)

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5 safety hazards

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2-Chloro-N-ethylacetamide (105-35-1)

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2-Bromo-N-ethylacetamide (5327-00-4)

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n-dodecylformamide (7402-57-5)

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N,N-Dimethylacrylamide (2680-03-7)

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N-Formylglycine (2491-15-8)

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N,N-Dimethylpropionamide (758-96-3)

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2-Mercaptoacetamide (758-08-7)

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2-hydroxyacetamide (598-42-5)

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Propiolamide (7341-96-0)

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2-Bromoacetamide (683-57-8)

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FLUOROACETAMIDE (640-19-7)

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3 safety hazards

3 suppliers

Acethydrazide (1068-57-1)

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iodoacetamide (144-48-9)

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2-Chloro-N,N-dimethylacetamide (2675-89-0)

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N-METHYL-3-(METHYLAMINO)PROPANAMIDE HYDROCHLORIDE (57180-63-9)

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1,1,1-Trimethylhydrazinium iodide (3288-80-0)

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2-hydroxy-N,N-dimethylacetamide (14658-93-6)

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N,N-Diisopropylformamide (2700-30-3)

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2-bromo-n,n-dimethylacetamide (5468-77-9)

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3-hydroxy-N-methylpropanamide (6830-81-5)

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Triuret (556-99-0)

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N-tert-Butylacetamide (762-84-5)

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62637-93-8 (62637-93-8)

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N-Methyl-N-vinylacetamide (3195-78-6)

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N-METHYLFORMAMIDE

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