TERT-BUTYL FORMATE (762-75-4)

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Suppliers

• Sigma-Aldrich - TERT-BUTYL FORMATE
  99.80 - 345.00 USD
• Fisher Scientific - Search for TERT-BUTYL FORMATE
• TCI - Search for TERT-BUTYL FORMATE

Most-cited Publications

• Roles of tert-butyl formate, tert-butyl alcohol and acetone in the regulation of methyl tert-butyl ether degradation by Mycobacterium austroafricanum IFP 2012. (Applied Microbiology and Biotechnology, 2003)
• Hydrolysis of tert-butyl formate : Kinetics, products, and implications for the environmental impact of methyl tert-butyl ether (Environmental Toxicology and Chemistry, 1999)
• The ester bond. II. Nuclear magnetic-resonance studies of tert-butyl formate (The Journal of Physical Chemistry, 1972)
• Vibrational spectra and rotational isomerism of t-butyl formate (Journal of Molecular Structure, 1979)
• The free radical chemistry of tert-butyl formate: rate constants for hydroxyl radical, hydrated electron and hydrogen atom reaction in aqueous solution (Radiation Physics and Chemistry, 2002)
• Palladium-catalyzed synthesis of aldehydes from aryl halides and tert-butyl isocyanide using formate salts as hydride donors (RSC Advances, 2015)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H225: Highly Flammable liquid and vapor
  Danger Flammable liquids - Category 2
• H335: May cause respiratory irritation
  Warning Specific target organ toxicity, single exposure; Respiratory tract irritation - Category 3

Trends

Alternate Names

• t-butyl formate
• SMILES
  CC(C)(C)OC=O
• InChIKey
  RUPAXCPQAAOIPB-UHFFFAOYSA-N

External Links

• Pubchem - TERT-BUTYL FORMATE
• Wikipedia - Tert-Butyloxycarbonyl Group
  tert-Butyl formate, also known as formic acid tert-butylester and TBF, is a chemical compound with molecular formula C5H10O2. TBF is one of the possible daughter products of methyl tert-butyl ether biodegradation.

Synthesis

formic acid  +  2-Chloro-2-methylpropane (Ester from carboxilic acid(SN2))

tert-Butoxymethanol  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)

Synthesis of TERT-BUTYL FORMATE ›

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tert-Butyl methyl ether (1634-04-4)

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tert-Butyl carbamate (4248-19-5)

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ISOPROPYL ACETATE (108-21-4)

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35976-76-2 (35976-76-2)

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Di-tert-butyl ether (6163-66-2)

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tert-Butyl propionate (20487-40-5)

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tert-Butyl acrylate (1663-39-4)

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tert-Butyl 2-aminoacetate (6456-74-2)

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tert-Butyl propiolate (13831-03-3)

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tert-Butyl bromoacetate (5292-43-3)

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tert-Butyl chloroacetate (107-59-5)

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Isopropyl chloroformate (108-23-6)

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2-tert-Butoxyethanol (7580-85-0)

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tert-Butyl carbazate (870-46-2)

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tert-Butyl methylcarbamate (16066-84-5)

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36016-38-3 (36016-38-3)

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Isobutylene oxide (558-30-5)

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1,2-Diformyloxyethane (629-15-2)

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1,2-Propanediol diformate (53818-14-7)

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tert-butyl butanoate (2308-38-5)

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2-methoxy-2-methylpropan-1-amine (89282-70-2)

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Magnesium tert-butoxide (32149-57-8)

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tert-butyl pivalate (16474-43-4)

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tert-Butyl cyanoacetate (1116-98-9)

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ETHYL ACETATE (141-78-6)

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tert-Butyl Isobutyl ether (33021-02-2)

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Isopentyl formate (110-45-2)

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ISOPROPYL GLYCOLATE (623-61-0)

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Diisopropyl ether (108-20-3)

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METHYL ACETATE (79-20-9)

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Acetic anhydride-d6 (16649-49-3)

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Di-tert-butyl dicarbonate (24424-99-5)

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Isopropyl bromoacetate (29921-57-1)

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ISOPROPYL CHLOROACETATE (105-48-6)

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Di-tert-butyl oxalate (691-64-5)

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2-Isopropoxyethanamine (81731-43-3)

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3-tert-Butoxy-3-oxopropanoic acid (40052-13-9)

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tert-butyl vinylcarbamate (7150-72-3)

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tert-Butyl ethyl malonate (32864-38-3)

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tert-Butyl methyl malonate (42726-73-8)

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Di-tert-butyl malonate (541-16-2)

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(S)-2-Methoxypropan-1-ol (116422-39-0)

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Di-tert-butyl glutarate (43052-39-7)

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2-METHOXY-1-PROPANAMINE HYDROCHLORIDE (70807-90-8)

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1-tert-butoxy-2-propanol (57018-52-7)

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ETHYL CHLOROFORMATE (541-41-3)

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Propargyl acetate (627-09-8)

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METHYL ISOBUTYRATE (26161-42-2, 547-63-7)

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ISOBUTYL ACETATE (110-19-0)

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di-tert-Butyl acetylenedicarboxylate (66086-33-7)

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t-Butyl trifluoroacetate (400-52-2)

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tert-Butyl methacrylate (585-07-9)

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1 safety hazard

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13404-22-3 (13404-22-3)

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N-Boc-ethylenediamine (57260-73-8)

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79513-35-2 (79513-35-2)

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Poloxamer 188 (106392-12-5, 9003-11-6, 53637-25-5)

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Propylene oxide (75-56-9)

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2-Methylpropane-1,2-diol (558-43-0)

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16466-61-8 (16466-61-8)

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tert-Butyl 2-bromopropanoate (39149-80-9)

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ETHYL PROPIONATE (105-37-3)

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Hexyl formate (629-33-4)

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3-Methoxy-3-methylbutan-1-ol (56539-66-3)

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ETHYL ISOBUTYRATE (97-62-1)

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2-methoxypropanenitrile (33695-59-9)

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Di-tert-butyl Iminodicarboxylate (51779-32-9)

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tert-butyl acetoacetate (1694-31-1)

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Allyl acetate (591-87-7)

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PROPYL CARBAMATE (627-12-3)

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1-Methoxy-2-propyl acetate (108-65-6)

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tert-Butyl 3-hydroxybutanoate (90435-23-7)

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85363-04-8 (85363-04-8)

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2-Hydroxyethyl acetate (65071-98-9, 51901-33-8, 542-59-6)

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2-ETHOXY-PROPYLAMINE HYDROCHLORIDE (1184979-76-7)

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(3-methoxy-3-methylbutyl)amine (1268153-93-0)

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tert-butyl (2-iodoethyl)carbamate (122234-46-2)

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tert-butyl hydroxy(methyl)carbamate (19689-97-5)

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2-methoxy-2-methylpropanoic acid (13836-62-9)

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Methyl pivalate (598-98-1)

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ISOBUTYL CARBAMATE (543-28-2)

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2-Methoxyethyl acetate (32718-56-2, 110-49-6)

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2-Ethoxyethyl acetate (111-15-9)

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METHYL ACRYLATE (96-33-3)

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2-METHYL-3-BUTYN-2-OL (115-19-5)

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tert-butyl (3-aminopropyl)carbamate (75178-96-0)

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Isobutyl chloroformate (543-27-1)

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DIETHYL CARBONATE (105-58-8)

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METHYL THIOGLYCOLATE (2365-48-2)

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Glycine methyl ester hydrochloride (5680-79-5)

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METHYL PROPIOLATE (922-67-8)

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Methyl cyanoformate (17640-15-2)

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Vinyl Acetate (108-05-4, 85306-26-9)

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Methyl glycolate (96-35-5)

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2-METHYL-3-BUTEN-2-OL (115-18-4)

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1-amino-2-methylpropan-2-ol (2854-16-2)

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TERT-BUTYL FORMATE

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