Weight | 100.117 g/mol |
---|---|
Formula | C5H8O2 |
Hydrogen Acceptors | 2 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 2 |
Allyl acetate (591-87-7)
Score:
#962 in Physics
,
#2752 in Chemistry
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- Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition (Journal of the American Chemical Society, 2008)
- Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate (Journal of the American Chemical Society, 2008)
- anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: -Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents (Journal of the American Chemical Society, 2009)
- The Polymerization of Allyl Compounds. III. The Peroxide-induced Copolymerization of Allyl Acetate with Maleic Anhydride1 (Journal of the American Chemical Society, 1946)
- Stereochemistry of oxidative addition of an optically active allyl acetate to a palladium(0) complex (Journal of the American Chemical Society, 1983)
- The Polymerization of Allyl Compounds. II. Preliminary Kinetic Study of the Peroxide-Induced Polymerization of Allyl Acetate (Journal of the American Chemical Society, 1945)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - H225: Highly Flammable liquid and vapor
Danger Flammable liquids - Category 2 - H315: Causes skin irritation
Warning Skin corrosion/irritation - Category 2 - H330: Fatal if inhaled
Danger Acute toxicity, inhalation - Category 1, 2 -
SMILESCC(=O)OCC=C
-
InChIKeyFWZUNOYOVVKUNF-UHFFFAOYSA-N
- Pubchem - Allyl acetate
- Wikipedia - allyl acetate
Allyl acetate is an organic compound with formula C3H5OC(O)CH3. This colourless liquid is a precursor to especially allyl alcohol, which is a useful industrial intermediate. It is the acetate ester of allyl alcohol.
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Synthesis
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
Reactant
+
1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide
(Nicolaou IBX dehydrogenation)
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