| Weight | 167.002 g/mol |
|---|---|
| Formula | C4H7BrO2 |
| Hydrogen Acceptors | 2 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 0 |
| Rotatable Bonds | 2 |
Ethyl bromoacetate (105-36-2)
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- Sigma-Aldrich - Ethyl bromoacetate33.90 - 230.50 USD
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- TCI - Search for Ethyl bromoacetate
- Activation of zinc by trimethylchlorosilane. An improved procedure for the preparation of .beta.-hydroxy esters from ethyl bromoacetate and aldehydes or ketones (Reformatsky reaction) (Journal of Organic Chemistry, 1987)
- Alkylation of Heterocyclic Ketene Aminals with Benzyl Chloride and Ethyl Bromoacetate. Synthesis of Heterobicycles Containing LactamFused Diazaheterocycles (Chemische Berichte, 1989)
- Reaction of organoboranes with ethyl bromoacetate under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters via hydroboration (Journal of the American Chemical Society, 1968)
- Improved procedure for the Reformatsky reaction of aliphatic aldehydes and ethyl bromoacetate (Journal of Organic Chemistry, 1969)
- Nickel-catalyzed synthesis of arylacetic esters from arylzinc chlorides and ethyl bromoacetate (Organometallics, 1983)
- Base-induced .alpha.-alkenylation of ethyl bromoacetate, phenacyl bromide and chloroacetonitrile via B-trans-1-alkenyl-9-borabicyclo[3.3.1]nonanes (Journal of Organic Chemistry, 1986)
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Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - H226: Flammable liquid and vapor
Warning Flammable liquids - Category 3 - H300: Fatal if swallowed
Danger Acute toxicity, oral - Category 1, 2 - H330: Fatal if inhaled
Danger Acute toxicity, inhalation - Category 1, 2 -
SMILESCCOC(=O)CBr
-
InChIKeyPQJJJMRNHATNKG-UHFFFAOYSA-N
- Pubchem - Ethyl bromoacetate
- Wikipedia - ethyl bromoacetate
Ethyl bromoacetate is the chemical compound with the formula CH2BrCO2C2H5. It is the ethyl ester of bromoacetic acid and is prepared in two steps from acetic acid. It is a lachrymator and has a fruity, pungent odor.
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Synthesis
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
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Ethyl bromoacetate
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