Weight | 138.948 g/mol |
---|---|
Formula | C2H3BrO2 |
Hydrogen Acceptors | 1 |
Hydrogen Donors | 1 |
Aromatic Rings | 0 |
Rotatable Bonds | 1 |
BROMOACETIC ACID (79-08-3)
bromoacetate · monobromoacetate
Score:
#341 in Biochemistry
,
#1440 in Chemistry
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- Preparation of peptide-protein immunogens using N-succinimidyl bromoacetate as a heterobifunctional crosslinking reagent. (Analytical Biochemistry, 1986)
- The histidine residue in the active centre of ribonuclease: I. A specific reaction with bromoacetic acid (Journal of Molecular Biology, 1959)
- Highly enantioselective routes to darzens and acetate aldol products from achiral aldehydes and t-butyl bromoacetate (Tetrahedron Letters, 1991)
- Activation of zinc by trimethylchlorosilane. An improved procedure for the preparation of .beta.-hydroxy esters from ethyl bromoacetate and aldehydes or ketones (Reformatsky reaction) (Journal of Organic Chemistry, 1987)
- Adaptation of Xanthobacter autotrophicus GJ10 to bromoacetate due to activation and mobilization of the haloacetate dehalogenase gene by insertion element IS1247. (Journal of Bacteriology, 1995)
- A monobromoacetate dehalogenase from Pseudomonas cepacia MBA4 (Archives of Microbiology, 1988)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - H301: Toxic if swallowed
Danger Acute toxicity, oral - Category 3 - H314: Causes severe skin burns and eye damage
Danger Skin corrosion/irritation - Category 1A, B, C - H318: Causes serious eye damage
Danger Serious eye damage/eye irritation - Category 1 - H331: Toxic if inhaled
Danger Acute toxicity, inhalation - Category 3 - H401: Toxic to aquatic life
Hazardous to the aquatic environment, acute hazard - Category 2 - bromoacetate
- monobromoacetate
-
SMILESC(C(=O)O)Br
-
InChIKeyKDPAWGWELVVRCH-UHFFFAOYSA-N
- Pubchem - BROMOACETIC ACID
- Wikipedia - bromoacetic acid
Bromoacetic acid is the chemical compound with the formula CH2BrCO2H. This colorless solid is a relatively strong alkylating agent. Bromoacetic acid and its esters are widely used building blocks in organic synthesis, for example in pharmaceutical chemistry.
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Synthesis
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
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