Weight | 179.013 g/mol |
---|---|
Formula | C5H7BrO2 |
Hydrogen Acceptors | 2 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 2 |
Methyl 4-bromocrotonate (1117-71-1)
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- Reaction of methyl 4-bromocrotonate with lithium ester enolates: direct SN2 displacement vs. Michael-initiated ring closure (Journal of Organic Chemistry, 1983)
- Diastereoselective Reformatsky reaction of methyl 4-bromocrotonate with 1,2:5,6-di-O-isopropylidene--d-ribo-hexofuranos-3-ulose: application to novel bicyclic nucleosides (Tetrahedron, 2004)
- -Alkylation of methyl 4-bromocrotonate, a vinylogous darzens reaction (Tetrahedron Letters, 1972)
- Nickel-Catalyzed C-Br/C-H Bis-phenylation of Methyl 4-Bromocrotonate: A Stereoselective Entry to Methyl (E)-3,4-Diphenylbut-2-enoate (Synthetic Communications, 2015)
- The kinetics and mechanism of the pyrolysis elimination of methyl 4bromocrotonate (International Journal of Chemical Kinetics, 1988)
- STUDIES OF FUSED RING SYSTEMS I.REACTION OF 7-METHOXY-1-KETO-2-METHYL-1,2,3,4-TETRAHYDROPHENANTHRENE WITH METHYL -BROMOCROTONATE;SYNTHESIS OF DL-HOMOEQUILENIN AND DEGRADATION OF ITS METHYL ETHER INTO DL-EQUILENIN (Acta Chimica Sinica, 1955)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. -
SMILESCOC(=O)C=CCBr
-
InChIKeyRWIKCBHOVNDESJ-UHFFFAOYSA-N
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Synthesis
Reactant
+
dimethyl sulfide
(Corey-Kim oxidation of secondary alcohols)
Reactant
+
1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide
(Nicolaou IBX dehydrogenation)
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