| Weight | 122.171 g/mol |
|---|---|
| Formula | C7H10N2 |
| Hydrogen Acceptors | 2 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 1 |
| Rotatable Bonds | 1 |
4-Dimethylaminopyridine (1122-58-3)
4-DMAP
Score:
#1537 in Physics
,
#4598 in Chemistry
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- 4-dimethylaminopyridine: an efficient and selective catalyst for the silylation of alcohols (Tetrahedron Letters, 1979)
- The DMAPCatalyzed Acetylation of AlcoholsA Mechanistic Study (DMAP=4(Dimethylamino)pyridine) (Chemistry: A European Journal, 2005)
- Preparation of .beta.-keto esters by 4-DMAP-catalyzed ester exchange (Journal of Organic Chemistry, 1985)
- Thermoplastic cellulose-graft-poly(L-lactide) copolymers homogeneously synthesized in an ionic liquid with 4-dimethylaminopyridine catalyst. (Biomacromolecules, 2009)
- Homogeneous modification of cellulose with succinic anhydride in ionic liquid using 4-dimethylaminopyridine as a catalyst (Carbohydrate Polymers, 2009)
- Dicarbonates: Convenient 4-Dimethylaminopyridine Catalyzed Esterification Reagents (Synthesis, 1994)
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Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - 4-DMAP
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SMILESCN(C)C1=CC=NC=C1
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InChIKeyVHYFNPMBLIVWCW-UHFFFAOYSA-N
- Pubchem - 4-Dimethylaminopyridine
- Wikipedia - 4-dimethylaminopyridine
4-Dimethylaminopyridine (DMAP) is a derivative of pyridine with the chemical formula (CH3)2NC5H4N. This colourless solid is of interest because it is more basic than pyridine, owing to the resonance stabilisation from the NMe2 substituent. Because of its basicity, DMAP is a useful nucleophilic catalyst for a variety of reactions such as esterifications with anhydrides, the Baylis-Hillman reaction, hydrosilylations, tritylation, the Steglich rearrangement, Staudinger synthesis of -lactams and many more.
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