Weight | 67.091 g/mol |
---|---|
Formula | C4H5N |
Hydrogen Acceptors | 1 |
Hydrogen Donors | 0 |
Aromatic Rings | 0 |
Rotatable Bonds | 0 |
Methacrylonitrile (126-98-7, 25067-61-2)
Score:
#34 in Materials science
,
#450 in Physics
,
#1316 in Chemistry
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- Enantioselective addition of secondary phosphines to methacrylonitrile: catalysis and mechanism. (Journal of the American Chemical Society, 2005)
- Nickel(II)-catalyzed highly enantioselective hydrophosphination of methacrylonitrile. (Journal of the American Chemical Society, 2004)
- Syntheses and characterisation of graft copolymers of maize starch and methacrylonitrile (Carbohydrate Polymers, 2000)
- Infrared studies of stereoregular polymerization of methyl methacrylate and methacrylonitrile by organometallic compounds (Journal of Polymer Science Part A, 1968)
- Radiation grafted fuel cell membranes based on co-grafting of -methylstyrene and methacrylonitrile into a fluoropolymer base film (Journal of Membrane Science, 2009)
- Coloration in acrylonitrile and methacrylonitrile polymers (Journal of Polymer Science, 1958)
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Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - H225: Highly Flammable liquid and vapor
Danger Flammable liquids - Category 2 - H311: Toxic in contact with skin
Danger Acute toxicity, dermal - Category 3 - H331: Toxic if inhaled
Danger Acute toxicity, inhalation - Category 3 - H361: Suspected of damaging fertility or the unborn child
Warning Reproductive toxicity - Category 2 -
SMILESCC(=C)C#N
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InChIKeyGYCMBHHDWRMZGG-UHFFFAOYSA-N
- Pubchem - Methacrylonitrile
- Wikipedia - methacrylonitrile
Methacrylonitrile (or 2-Methylprop-2-enenitrile), MeAN in short, is a chemical compound that is an unsaturated aliphatic nitrile, widely used in the preparation of homopolymers, copolymers, elastomers, and plastics and as a chemical intermediate in the preparation of acids, amides, amines, esters, and other nitriles. MeAN is also used as a replacement for acrylonitrile in the manufacture of an acrylonitrile/butadiene/styrene-like polymer. It is a clear and colorless (to slightly yellow) liquid, that has a bitter almond smell.
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Synthesis
Reactant
+
1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide
(Nicolaou IBX dehydrogenation)
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