METHYL FORMATE (107-31-3)

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Suppliers

• Sigma-Aldrich - METHYL FORMATE
  40.00 - 279.00 USD
• Fisher Scientific - Search for METHYL FORMATE
• TCI - METHYL FORMATE
  14.00 - 123.00 USD

Most-cited Publications

• Formation of methyl formate and other organic species in the warm-up phase of hot molecular cores (Astronomy and Astrophysics, 2006)
• Barriers to rotation adjacent to double bonds. 3. The C-O barrier in formic acid, methyl formate, acetic acid, and methyl acetate. The origin of ester and amide resonance (Journal of the American Chemical Society, 1987)
• Microwave Spectrum, Barrier to Internal Rotation, and Structure of Methyl Formate (Journal of Chemical Physics, 1959)
• A spectroscopic study of the adsorption and reactions of methanol, formaldehyde and methyl formate on clean and oxygenated Cu(110) surfaces (Surface Science, 1985)
• A vibrational assignment for methyl formate and methyl acetate (Journal of Molecular Spectroscopy, 1957)
• An Electron Diffraction Investigation of Methyl Formate, Methyl Acetate and Methyl Chloroformate (Journal of the American Chemical Society, 1950)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H224: Extremely flammable liquid and vapor
  Danger Flammable liquids - Category 1
• H315: Causes skin irritation
  Warning Skin corrosion/irritation - Category 2
• H319: Causes serious eye irritation
  Warning Serious eye damage/eye irritation - Category 2A
• H335: May cause respiratory irritation
  Warning Specific target organ toxicity, single exposure; Respiratory tract irritation - Category 3
• H370: Causes damage to organs
  Danger Specific target organ toxicity, single exposure - Category 1

Trends

Alternate Names

• methyl formate, formic-18O-acid-O-methyl-labeled
• methyl formate, hydride
• methyl formate, 18O-methyl ester-labeled
• SMILES
  COC=O
• InChIKey
  TZIHFWKZFHZASV-UHFFFAOYSA-N

External Links

• Pubchem - METHYL FORMATE
• Wikipedia - methyl formate
  Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. The simplest example of an ester, it is a colorless liquid with an ethereal odour, high vapor pressure, and low surface tension. It is a precursor to many other compounds of commercial interest.

Synthesis

Methoxymethanol  +  dimethyl sulfide (Corey-Kim oxidation of secondary alcohols)

Synthesis of METHYL FORMATE ›

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ETHYLENE GLYCOL (9003-11-6, 107-21-1, 25322-68-3, 37225-26-6)

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dimethyl sulfide (31533-72-9, 75-18-3)

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trans-2-Butene (590-18-1 (cis isomer), 624-64-6, 107-01-7, 68956-54-7)

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METHYL FORMATE

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