| Weight | 325.233 g/mol |
|---|---|
| Formula | C16H14CoN2O2 |
| Hydrogen Acceptors | 4 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 2 |
| Rotatable Bonds | 5 |
Salcomin (14167-18-1)
N,N-ethylenebis(salicylideneiminato)cobalt(II) · salcomine
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- The synthesis of some intermediates for use in the preparation of analogs of salicylaldehyde ethylenediimine cobalt (salcomine) (Journal of Organic Chemistry, 1946)
- Salcomine-catalyzed oxidations of some phenols: A new method for the preparation of a number of para-benzoquinones (Recueil des Travaux Chimiques des Pays-Bas, 2010)
- A Convenient Synthesis of Juglone Via Neutral Salcomine Oxidation (Synthetic Communications, 1984)
- The Autoxidation of Phenols Catalyzed by Phthalocyanine-Fe(II) and Salcomine-pyridine (Bulletin of the Chemical Society of Japan, 1972)
- Catalytic oxidation of 2,6-di-t-butylphenol by salcomine-type complexes in the presence of water (Tetrahedron Letters, 1976)
- The synthesis of the pyranonaphthoquinones dehydroherbarin and anhydrofusarubin using Wacker oxidation methodology as a key step and other unexpected oxidation reactions with ceric ammonium nitrate and salcomine (Organic and Biomolecular Chemistry, 2012)
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Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - N,N-ethylenebis(salicylideneiminato)cobalt(II)
- salcomine
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SMILESC1=CC=C(C(=C1)C=NCCN=CC2=CC=CC=C2[O-])[O-].[Co+2]
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InChIKeyNPAQSKHBTMUERN-UHFFFAOYSA-L
- Pubchem - Salcomin
- Wikipedia - Salcomine
Salcomine is a coordination complex derived from the salen ligand and cobalt. The complex, which is planar, and a variety of its derivatives are carriers for O2 as well as oxidation catalysts.
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Synthesis
2-formylphenolate
+
Reactant
(Imine formation from aldehyde)
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Salcomin
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