trans-1,4-Dichloro-2-butene

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Suppliers

• Sigma-Aldrich - trans-1,4-Dichloro-2-butene
  53.80 - 213.50 USD
• Fisher Scientific - Search for trans-1,4-Dichloro-2-butene
• TCI - Search for trans-1,4-Dichloro-2-butene

Most-cited Publications

• Notes: Amination Reactions of cis-1,4-Dichloro-2-butene (Journal of Organic Chemistry, 1960)
• Improved synthesis of 3-cyclopentene-1-carboxylic acid from 1,4-dichloro-2-butene (Journal of Organic Chemistry, 1967)
• Poly(p-phenylene) from p-dibromobenzene, magnesium, and 1,4-dichloro-2-butene (Journal of Polymer Science: Polymer Letters Edition, 1981)
• 1,3-Dipolar cycloaddition of a chiral nitrone to (E)-1,4-dichloro-2-butene: a new efficient synthesis of (2S,3S,4R)-4-hydroxyisoleucine (Tetrahedron Letters, 2012)
• Unsaturated macrocyclic compounds. LVIII. Reaction of trans-1,4-dibromo-2-butene and trans-1,4-dichloro-2-butene with ethynylmagnesium bromide. Synthesis of precursors of fully conjugated 14-, 16-, 20-, and 26-membered ring cyclic compounds (Journal of the American Chemical Society, 1968)
• Reactions of cis- and trans-1,4-dichloro-2-butene with sodium amide (Journal of Organic Chemistry, 1968)

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H226: Flammable liquid and vapor
  Warning Flammable liquids - Category 3
• H301: Toxic if swallowed
  Danger Acute toxicity, oral - Category 3
• H311: Toxic in contact with skin
  Danger Acute toxicity, dermal - Category 3
• H314: Causes severe skin burns and eye damage
  Danger Skin corrosion/irritation - Category 1A, B, C
• H318: Causes serious eye damage
  Danger Serious eye damage/eye irritation - Category 1
• H341: Suspected of causing genetic defects
  Warning Germ cell mutagenicity - Category 2
• H350: May cause cancer
  Danger Carcinogenicity - Category 1A, 1B
• H370: Causes damage to organs
  Danger Specific target organ toxicity, single exposure - Category 1
• H400: Very toxic to aquatic life
  Warning Hazardous to the aquatic environment, acute hazard - Category 1
• H410: Very toxic to aquatic life with long lasting effects
  Warning Hazardous to the aquatic environment, long-term hazard - Category 1

Trends

Alternate Names

• 1,4-dichloro-2-butene, (E)-isomer
• 1,4-dichloro-2-butene
• 1,4-dichloro-2-butene, (Z)-isomer
• SMILES
  C(C=CCCl)Cl
• InChIKey
  FQDIANVAWVHZIR-UHFFFAOYSA-N

External Links

• Pubchem - trans-1,4-Dichloro-2-butene
• Wikipedia - 1,4-Dichlorobut-2-ene
  1,4-Dichlorobut-2-ene is a chlorinated butene. It is an intermediate in the industrial production of chloroprene, and the main impurity in technical grade chloroprene. The (E)-isomer is also one of the starting materials for Birman's total synthesis of the poriferic natural product sceptrin.

Synthesis

CHLOROACETALDEHYDE  +  1,2-dichloroethane (Wittig)

ALLYL CHLORIDE  +  Dichloromethane (Heck terminal vinyl)

Synthesis of trans-1,4-Dichloro-2-butene ›

Similar Compounds

cis-1,4-Dichloro-2-butene (764-41-0, 1476-11-5)

4 alternate names

10 safety hazards

3 suppliers

1,4-DICHLORO-2-BUTENE (764-41-0, 1476-11-5)

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1,3-DICHLOROPROPENE (10061-02-6, 542-75-6)

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cis-3-Chloroallyl Chloride (542-75-6)

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cis-1,3-DICHLOROPROPENE (10061-01-5, 542-75-6)

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TRANS-1,2-DICHLOROETHYLENE (540-59-0, 156-60-5)

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cis-1,2-Dichloroethene (540-59-0, 156-59-2)

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CIS-1,2-DICHLOROETHYLENE (540-59-0, 156-59-2)

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1,2-Dichloroethylene (540-59-0)

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Ethene, 1,2-dichloro- (540-59-0)

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1,3-DICHLORO-2-BUTENE (10075-38-4, 926-57-8)

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1,3-Dichlorobut-2-ene (10075-38-4, 7415-31-8, 926-57-8)

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2-Butene, 1,3-dichloro- (10075-38-4, 926-57-8)

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1,1-DICHLOROPROPENE (26952-23-8, 563-58-6)

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Vinylidene chloride (75-35-4, 25323-30-2, 9002-85-1)

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1,2,3-TRICHLOROPROPANE (96-18-4)

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1,1,2-TRICHLOROETHANE (79-00-5)

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BIS(CHLOROMETHYL) ETHER (542-88-1)

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CHLOROACETYL CHLORIDE (79-04-9)

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Dichloroethyne (7572-29-4)

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1,1-DICHLOROPROPANE (26638-19-7, 78-99-9)

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3,4-DICHLORO-1-BUTENE (760-23-6)

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1,2-DICHLOROPROPENE (563-54-2)

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1,6-DICHLOROHEXANE (2163-00-0)

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TRICHLOROETHYLENE (79-01-6)

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1,1-DICHLOROETHANE (1300-21-6, 75-34-3)

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PHOSPHORUS TRICHLORIDE (7719-12-2, 10025-87-3)

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CHLOROACETALDEHYDE (107-20-0)

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1,3-DICHLOROPROPANE (142-28-9)

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1,3-DICHLORO-2-PROPANOL (96-23-1)

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1-CHLOROPENTANE (29656-63-1, 543-59-9)

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THIOPHOSGENE (463-71-8)

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1,4-HEXADIENE (592-45-0, 7319-00-8)

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1,2-BIS(2-CHLOROETHOXY)ETHANE (27252-69-3, 112-26-5)

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DICHLOROACETALDEHYDE (79-02-7)

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2,3-Dichloro-1-propanol (616-23-9)

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1-CHLOROOCTANE (111-85-3, 57214-71-8)

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2-Butene-1,4-diol (6117-80-2, 110-64-5, 29733-86-6, 821-11-4)

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110-64-5 (6117-80-2, 110-64-5, 29733-86-6)

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cis-2-Butene-1,4-Diol (29733-86-6, 110-64-5, 6117-80-2)

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2-butene-1,4-diol, (2Z)- (6117-80-2, 110-64-5, 29733-86-6)

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CHLOROCYCLOHEXANE (542-18-7)

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1-CHLOROHEXANE (70776-07-7, 544-10-5, 25495-90-3)

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Chloromethyl chloroformate (22128-62-7)

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1,4-Dibromo-2-butene (6974-12-5, 821-06-7)

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chloroacetic acid (79-11-8)

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2-chloroethanol (107-07-3)

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Disulfur dichloride (10025-67-9, 12771-08-3)

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DECANE (73138-29-1, 124-18-5, 63335-87-5)

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2-Methylbutane (78-78-4)

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THIONYL CHLORIDE (7719-09-7)

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thiodiglycol (111-48-8)

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DIETHYLENETRIAMINE (111-40-0)

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CHLOROACETONITRILE (107-14-2)

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DIMETHYLCARBAMOYL CHLORIDE (79-44-7)

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2-Butyne-1,4-diol (110-65-6)

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Cyclopentadiene (542-92-7)

4 alternate names

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4 alternate names

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Undecane (61193-21-3, 1120-21-4)

4 alternate names

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3 suppliers

1,1-DICHLORO-1-FLUOROETHANE (1717-00-6)

4 alternate names

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3 suppliers

METHYLCYCLOHEXANE (108-87-2)

4 alternate names

4 safety hazards

3 suppliers

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trans-1,4-Dichloro-2-butene

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