| Weight | 179.204 g/mol |
|---|---|
| Formula | C6H18N3OP |
| Hydrogen Acceptors | 1 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 0 |
| Rotatable Bonds | 3 |
HEXAMETHYLPHOSPHORAMIDE (630-31-9, 680-31-9)
HMPA · Hexamethylphosphoric Triamide · Hempa
Score:
#551 in Physics
,
#1600 in Chemistry
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- Me3SiCl/HMPA accelerated conjugate addition of catalytic copper reagent. Stereoselective synthesis of enol silyl ether of aldehyde (Tetrahedron Letters, 1986)
- A mild and convenient method for the reduction of organic halides by using a SmI2-THF solution in the presence of hexamethylphosphoric triamide(HMPA). (Chemistry Letters, 1987)
- Characterization of sulfur radical anions in solutions of alkali polysulfides in dimethylformamide and hexamethylphosphoramide and in the solid state in ultramarine blue, green, and red (Inorganic Chemistry, 1978)
- Electrochemical investigation of the reducing power of SmI2 in THF and the effect of HMPA cosolvent (Tetrahedron Letters, 1997)
- A Novel Optical Complex between an Organic Substrate and a Polyoxometalate. Crystal and Molecular Structure of -H4SiW12O404HMPA2H2O (HMPA = Hexamethylphosphoramide) (Inorganic Chemistry, 1996)
- Methylcopper(I)-catalyzed selective conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds by di-iso-butylaluminum hydride in the presence of hexamethylphosphoric triamide (Journal of Organic Chemistry, 1986)
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Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - H303: May be harmful if swallowed
Warning Acute toxicity, oral - Category 5 - H315: Causes skin irritation
Warning Skin corrosion/irritation - Category 2 - H340: May cause genetic defects
Danger Germ cell mutagenicity - Category 1A, 1B - H351: Suspected of causing cancer
Warning Carcinogenicity - Category 2 - H371: May cause damage to organs
Warning Specific target organ toxicity, single exposure - Category 2 - HMPA
- Hexamethylphosphoric Triamide
- Hempa
- Hexametapol
-
SMILESCN(C)P(=O)(N(C)C)N(C)C
-
InChIKeyGNOIPBMMFNIUFM-UHFFFAOYSA-N
- Pubchem - HEXAMETHYLPHOSPHORAMIDE
- Wikipedia - hexamethylphosphoramide triamide
Hexamethylphosphoramide, often abbreviated HMPA, is a phosphoramide (i.e. an amide of phosphoric acid) with the formula [(CH3)2N]3PO. This colorless liquid is a useful polar aprotic solvent and additive in organic synthesis.
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