| Weight | 172.188 g/mol |
|---|---|
| Formula | C6H12N4O2 |
| Hydrogen Acceptors | 2 |
| Hydrogen Donors | 0 |
| Aromatic Rings | 0 |
| Rotatable Bonds | 0 |
DIAMIDE (302-01-2, 10465-78-8)
Diazodicarboxylic Acid Bisdimethylamide · Tetramethylazoformamide · Dizene Dicarboxylic Acid Bis(N,N-dimethylamide)
Score:
#1337 in Biochemistry
,
#3254 in Biology
,
#4064 in Chemistry
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- Diamide, a new reagent for the intracellular oxidation of glutathione to the disulfide (Biochemical and Biophysical Research Communications, 1969)
- Rynaxypyr: A new insecticidal anthranilic diamide that acts as a potent and selective ryanodine receptor activator (Bioorganic & Medicinal Chemistry Letters, 2007)
- Conformation-directing effects of a single intramolecular amide-amide hydrogen bond : variable-temperature NMR and IR studies on a homologous diamide series (Journal of the American Chemical Society, 1991)
- Diamide: an oxidant probe for thiols. (Methods in Enzymology, 1995)
- Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts (Organometallics, 1996)
- REDOX REGULATION OF UBIQUITIN-CONJUGATING ENZYMES : MECHANISTIC INSIGHTS USING THE THIOL-SPECIFIC OXIDANT DIAMIDE (The FASEB Journal, 1998)
-
Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - Diazodicarboxylic Acid Bisdimethylamide
- Tetramethylazoformamide
- Dizene Dicarboxylic Acid Bis(N,N-dimethylamide)
- Dizenedicarboxylic Acid Bis(N,N-dimethylamide)
- Diazodicarboxylic Acid Bis(N,N-dimethyl)amide
-
SMILESCN(C)C(=O)N=NC(=O)N(C)C
-
InChIKeyVLSDXINSOMDCBK-UHFFFAOYSA-N
- Pubchem - DIAMIDE
- Wikipedia - 1,1'-azobis(N,N-dimethylformamide)
Tetramethylazodicarboxamide (TMAD) is a reagent used in biochemistry for oxidation of thiols in proteins to disulfides. It has also been used as a reagent in the Mitsunobu reaction in place of diethyl azodicarboxylate.
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Synthesis
Reactant
+
Dimethylamine
(Schotten-Baumann amide from acid)
Methylboronic acid
+
Reactant
(Chan-Lam coupling reaction)
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DIAMIDE
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