N,N-Diethyl-3-methylbenzamide (111-40-0, 134-62-3)

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Suppliers

• Sigma-Aldrich - N,N-Diethyl-3-methylbenzamide
  24.70 - 338.10 USD
• Fisher Scientific - Search for N,N-Diethyl-3-methylbenzamide
• TCI - N,N-Diethyl-3-methylbenzamide
  14.00 - 60.00 USD

Most-cited Publications

• The DET Curve in Assessment of Detection Task Performance (Conference of the International Speech Communication Association, 1997)
• Log-det heuristic for matrix rank minimization with applications to Hankel and Euclidean distance matrices (American Control Conference, 2003)
• The projectivity of the moduli space of stable curves. I: Preliminaries on "det" and "Div". (Mathematica Scandinavica, 1976)
• A Role for Cytokinins in De-Etiolation in Arabidopsis (det Mutants Have an Altered Response to Cytokinins) (Plant Physiology, 1994)
• Diffusional characteristics of hydrogels used in DGT and DET techniques. (Analytica Chimica Acta, 1999)
• Drugs and personal care products as ubiquitous pollutants: occurrence and distribution of clofibric acid, caffeine and DEET in the North Sea (Science of The Total Environment, 2002)

Areas of Application

Safety

• Request a Demo
  Predict GHS Hazards for Any Chemical in silico.
  Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more.
• H302: Harmful if swallowed
  Warning Acute toxicity, oral - Category 4
• H315: Causes skin irritation
  Warning Skin corrosion/irritation - Category 2
• H319: Causes serious eye irritation
  Warning Serious eye damage/eye irritation - Category 2A
• H336: May cause drowsiness or dizziness
  Warning Specific target organ toxicity, single exposure; Narcotic effects - Category 3

Trends

Alternate Names

• DET
• DEET
• DETA
• R 209
• R209
• N,N Diethyltoluamide
• N,N-Diethyl-2,5-dimethylbenzamide
• N,N-Diethyl-m-toluamide
• R-209
• DEET, 2,5-di-Me-Analog
• N,N Diethyl m toluamide
• N,N-Diethyltoluamide
• N,N Diethyl 3 methylbenzamide
• SMILES
  CCN(CC)C(=O)C1=CC(=CC=C1)C
• InChIKey
  MMOXZBCLCQITDF-UHFFFAOYSA-N

Estimated Properties

External Links

• Pubchem - N,N-Diethyl-3-methylbenzamide
• Wikipedia - diethyltoluamide
  N,N-Diethyl-meta-toluamide, also called DEET () or diethyltoluamide, is the most common active ingredient in insect repellents. It is a slightly yellow oil intended to be applied to the skin or to clothing, and provides protection against mosquitoes, ticks, fleas, chiggers, leeches, and many biting insects.

Synthesis

3-Methylbenzoyl chloride  +  DIETHYLAMINE (Schotten-Baumann amide from acid)

Ethylboronic acid  +  N-ethyl-3-methylbenzamide (Chan-Lam coupling reaction)

Synthesis of N,N-Diethyl-3-methylbenzamide ›

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