| Weight | 268.316 g/mol |
|---|---|
| Formula | C16H16N2O2 |
| Hydrogen Acceptors | 4 |
| Hydrogen Donors | 2 |
| Aromatic Rings | 0 |
| Rotatable Bonds | 5 |
Salen (14167-18-1, 94-93-9)
tetrahydrosalen · N,N'-bis(salicylideneamino)ethane · disalicylaldehyde ethylenediamine
Score:
#1368 in Physics
,
#3985 in Chemistry
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- Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes (Journal of the American Chemical Society, 1990)
- MetalSalen Schiff Base Complexes in Catalysis: Practical Aspects (Chemical Society Reviews, 2004)
- Making plastics from carbon dioxide: salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2. (Chemical Reviews, 2007)
- Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts (Coordination Chemistry Reviews, 1995)
- Highly Selective Hydrolytic Kinetic Resolution of Terminal Epoxides Catalyzed by Chiral (salen)CoIII Complexes. Practical Synthesis of Enantioenriched Terminal Epoxides and 1,2-Diols (Journal of the American Chemical Society, 2002)
- Utilisation of homogeneous and supported chiral metal(salen) complexes in asymmetric catalysis (Chemical Society Reviews, 1999)
-
Predict GHS Hazards for Any Chemical in silico.
Including Acute Oral Tox, Skin Sensitization, Eye Irritation, Aquatic Tox, & more. - tetrahydrosalen
- N,N'-bis(salicylideneamino)ethane
- disalicylaldehyde ethylenediamine
- N,N'-ethylenebis(salicylimine)
-
SMILESC1=CC(=CNCCNC=C2C=CC=CC2=O)C(=O)C=C1
-
InChIKeyRQHVNNWVDLRULK-UHFFFAOYSA-N
- Pubchem - Salen
- Wikipedia - Salen ligand
Salen is the abbreviation for a popular chelating ligand used in coordination chemistry and homogeneous catalysis. The name salen is a contraction for salicylaldehyde and ethylenediamine. The ligand is a bright yellow micaceous solid that is soluble in polar organic solvents.
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Synthesis
NSC92396
+
Reactant
(Alkylation of primary amines)
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